Uranium speciation in plants

Verfasser / Beitragende:
[A. Günther, G. Bernhard, G. Geipel, T. Reich, A. Roßberg, H. Nitsche]
Ort, Verlag, Jahr:
2003
Enthalten in:
Radiochimica Acta/International journal for chemical aspects of nuclear science and technology, 91/6/2003(2003-06-01), 319-328
Format:
Artikel (online)
ID: 378847252
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024 7 0 |a 10.1524/ract.91.6.319.20022  |2 doi 
035 |a (NATIONALLICENCE)gruyter-10.1524/ract.91.6.319.20022 
245 0 0 |a Uranium speciation in plants  |h [Elektronische Daten]  |c [A. Günther, G. Bernhard, G. Geipel, T. Reich, A. Roßberg, H. Nitsche] 
520 3 |a Detailed knowledge of the nature of uranium complexes formed after the uptake by plants is an essential prerequisite to describe the migration behavior of uranium in the environment. This study focuses on the determination of uranium speciation after uptake of uranium by lupine plants. For the first time, time-resolved laser-induced fluorescence spectroscopy and X-ray absorption spectroscopy were used to determine the chemical speciation of uranium in plants. Differences were detected between the uranium speciation in the initial solution (hydroponic solution and pore water of soil) and inside the lupine plants. The oxidation state of uranium did not change and remained hexavalent after it was taken up by the lupine plants. The chemical speciation of uranium was identical in the roots, shoot axis, and leaves and was independent of the uranium speciation in the uptake solution. The results indicate that the uranium is predominantly bound as uranyl(VI) phosphate to the phosphoryl groups. Dandelions and lamb´s lettuce showed uranium speciation identical to lupine plants. 
540 |a © 2003 Oldenbourg Wissenschaftsverlag GmbH 
690 7 |a Laboratory techniques, experiments  |2 nationallicence 
690 7 |a Analytical chemistry  |2 nationallicence 
690 7 |a Inorganic chemistry  |2 nationallicence 
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700 1 |a Bernhard  |D G.  |4 aut 
700 1 |a Geipel  |D G.  |4 aut 
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700 1 |a Roßberg  |D A.  |4 aut 
700 1 |a Nitsche  |D H.  |4 aut 
773 0 |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology  |d Oldenbourg Wissenschaftsverlag GmbH  |g 91/6/2003(2003-06-01), 319-328  |x 0033-8230  |q 91:6/2003<319  |1 2003  |2 91  |o ract 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Geipel  |D G.  |4 aut 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Nitsche  |D H.  |4 aut 
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