Crystal structure of new hexahydrate dicobalt pyrophosphate Co2P2O7·6H2O: comparison with Co2P2O72H2O, α-, β- and γ-Co2P2O7
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| 024 | 7 | 0 | |a 10.1524/zkri.218.5.345.20738 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.218.5.345.20738 | ||
| 245 | 0 | 0 | |a Crystal structure of new hexahydrate dicobalt pyrophosphate Co2P2O7·6H2O: comparison with Co2P2O72H2O, α-, β- and γ-Co2P2O7 |h [Elektronische Daten] |c [F. Capitelli, M. Harcharras, H. Assaaoudi, A. Ennaciri, A. G. G. Moliterni, V. Bertolasi] |
| 520 | 3 | |a A new dicobalt pyrophosphate, Co2P2O7·6H2O, has been synthesized and characterized by single crystal X-ray diffraction. The compound belongs to the mono clinic space group P21/n, and its unit cell dimensions are: a = 7.2077(2), b = 18.3373(5), c = 7.6762(2) Å, β = 92.4356(15)°, V = 1013.64(5) Å3, Z = 4. The structural parameters were refined to an R index of 0.0570 for 1937 reflections with I>2σ(Io). The framework of this pyro phosphate is made by the packing of layers of discrete CoO6 octahedra connected by double tetrahedra P2O7 groups. The (P2O7)4- anion group shows bent eclipsed conformation. A comparative study among anhydrous (α-, β- and γ-Co2P2O7) and hydrated forms (Co2P2O7·2H2O) of dicobalt pyrophosphates known in literature is presented. | |
| 540 | |a © 2003 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Capitelli |D F. |4 aut | |
| 700 | 1 | |a Harcharras |D M. |4 aut | |
| 700 | 1 | |a Assaaoudi |D H. |4 aut | |
| 700 | 1 | |a Ennaciri |D A. |4 aut | |
| 700 | 1 | |a Moliterni |D A. G. G. |4 aut | |
| 700 | 1 | |a Bertolasi |D V. |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 218/5(2003-05-01), 345-350 |x 2194-4946 |q 218:5<345 |1 2003 |2 218 |o zkri | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zkri.218.5.345.20738 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.218.5.345.20738 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Capitelli |D F. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Harcharras |D M. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Assaaoudi |D H. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ennaciri |D A. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Moliterni |D A. G. G. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Bertolasi |D V. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 218/5(2003-05-01), 345-350 |x 2194-4946 |q 218:5<345 |1 2003 |2 218 |o zkri | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||