Crystal structures and Raman spectra of Cu(OH)F and Cu3(OH)2F4
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| 024 | 7 | 0 | |a 10.1524/zkri.218.5.351.20735 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.218.5.351.20735 | ||
| 245 | 0 | 0 | |a Crystal structures and Raman spectra of Cu(OH)F and Cu3(OH)2F4 |h [Elektronische Daten] |c [G. Giester, E. Libowitzky] |
| 520 | 3 | |a Crystals of Cu(OH)F and Cu3(OH)2F4 have been synthesized at low-hydrothermal conditions in sizes up to 0.3 mm. The structures were solved from CCD X-ray single-crystal data and refined to R = 0.033 and 0.019, respectively. Cu(OH)F: space group P21/a, Z = 4, a = 5.301(1) Å, b = 6.376(1) Å, c = 5.074(1) Å, β = 112.90(1)°, and V = 157.98(5) Å3. Cu3(OH)2F4: space group P21/n, Z = 2, a = 5.501(1) Å, b = 4.766(1) Å, c = 8.462(1) Å, β = 92.28(1)°, and V = 221.68(7) Å3. In both compounds the copper atoms are 4 + 2 coordinated to their ligands (Jahn-Teller distortion). Cu(OH)F is isotypic to Cu(OH)Cl, forming layers of edge-sharing Cu(OH)3F3 polyhedra, which are interconnected by hydrogen bonds. The structure of Cu3(OH)2F4 is characterized by chains of edge-sharing Cu(OH)2F4 polyhedra running along [1 0 0], which are linked to each other via corners to form a framework. Hydrogen bonds of the type O—H···F occur with O···F distances of 2.619 and 2.697 Å in Cu(OH)Fand Cu3(OH)2F4, respectively. The observed O—H stretching frequencies of 3129 and 3306 cm-1, respectively, in Raman spectra are in excellent agreement with expected values from distance — frequency correlations. Moreover, the pleochroism of the bands corresponds in both compounds to the O—H orientation found in the structure determination. | |
| 540 | |a © 2003 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Giester |D G. |4 aut | |
| 700 | 1 | |a Libowitzky |D E. |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 218/5(2003-05-01), 351-356 |x 2194-4946 |q 218:5<351 |1 2003 |2 218 |o zkri | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zkri.218.5.351.20735 |q text/html |z Onlinezugriff via DOI |
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| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.218.5.351.20735 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Giester |D G. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Libowitzky |D E. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 218/5(2003-05-01), 351-356 |x 2194-4946 |q 218:5<351 |1 2003 |2 218 |o zkri | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||