Crystal structure of an inclusion complex between chiral monoaza-15-crown-5 and S(-)-1-phenyl-ethyl ammonium percholorate
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| 024 | 7 | 0 | |a 10.1524/zkri.218.5.381.20734 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.218.5.381.20734 | ||
| 245 | 0 | 0 | |a Crystal structure of an inclusion complex between chiral monoaza-15-crown-5 and S(-)-1-phenyl-ethyl ammonium percholorate |h [Elektronische Daten] |c [Süheyla Özbey, F. B. Kaynak, M. Toğrul, N. Demirel, H. Hoşgören] |
| 520 | 3 | |a A new type of inclusion complex, S(-)-1 phenyl ethyl ammonium percholorate complex of R-(-)-2-ethyl - N - benzyl - 4, 7, 10, 13 - tetraoxa -1- azacyclopentadecane, has been prepared and studied by NMR, IR and single crystal X-ray diffraction techniques. The compound crystallizes in space group P21 with cell dimensions a = 10.0000(8), b = 12.281(2), c = 12.331(1)Å, β = 102.052(7), Z = 2 The host-guest complex is held together by a strong system of hydrogen bonds between the two protons of the ammonium ion as well as the nitrogen and four oxygen atoms of the crown ether The C—O and C—C distances of the 15-membered ring average 1.418 and 1.501 Å while the O—C—C and C—O—C angles average 110.2 and 113.3°. The average N—C distance is 1.476 Å. | |
| 540 | |a © 2003 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Özbey |D Süheyla |4 aut | |
| 700 | 1 | |a Kaynak |D F. B. |4 aut | |
| 700 | 1 | |a Toğrul |D M. |4 aut | |
| 700 | 1 | |a Demirel |D N. |4 aut | |
| 700 | 1 | |a Hoşgören |D H. |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 218/5(2003-05-01), 381-384 |x 2194-4946 |q 218:5<381 |1 2003 |2 218 |o zkri | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zkri.218.5.381.20734 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.218.5.381.20734 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Özbey |D Süheyla |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kaynak |D F. B. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Toğrul |D M. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Demirel |D N. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Hoşgören |D H. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 218/5(2003-05-01), 381-384 |x 2194-4946 |q 218:5<381 |1 2003 |2 218 |o zkri | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||