caa a22 4500 378854836 CHVBK 20180305123332.0 cr unu---uuuuu 161128e20030501xx s 000 0 eng 10.1524/zkri.218.5.381.20734 doi (NATIONALLICENCE)gruyter-10.1524/zkri.218.5.381.20734 Crystal structure of an inclusion complex between chiral monoaza-15-crown-5 and S(-)-1-phenyl-ethyl ammonium percholorate [Elektronische Daten] [Süheyla Özbey, F. B. Kaynak, M. Toğrul, N. Demirel, H. Hoşgören] A new type of inclusion complex, S(-)-1 phenyl ethyl ammonium percholorate complex of R-(-)-2-ethyl - N - benzyl - 4, 7, 10, 13 - tetraoxa -1- azacyclopentadecane, has been prepared and studied by NMR, IR and single crystal X-ray diffraction techniques. The compound crystallizes in space group P21 with cell dimensions a = 10.0000(8), b = 12.281(2), c = 12.331(1)Å, β = 102.052(7), Z = 2 The host-guest complex is held together by a strong system of hydrogen bonds between the two protons of the ammonium ion as well as the nitrogen and four oxygen atoms of the crown ether The C—O and C—C distances of the 15-membered ring average 1.418 and 1.501 Å while the O—C—C and C—O—C angles average 110.2 and 113.3°. The average N—C distance is 1.476 Å. © 2003 Oldenbourg Wissenschaftsverlag GmbH Crystallography nationallicence Inorganic chemistry nationallicence Organic chemistry nationallicence Özbey Süheyla aut Kaynak F. B. aut Toğrul M. aut Demirel N. aut Hoşgören H. aut Zeitschrift für Kristallographie - Crystalline Materials De Gruyter Oldenbourg 218/5(2003-05-01), 381-384 2194-4946 218:5<381 2003 218 zkri https://doi.org/10.1524/zkri.218.5.381.20734 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zkri.218.5.381.20734 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Özbey Süheyla aut NATIONALLICENCE 700 1- Kaynak F. B. aut NATIONALLICENCE 700 1- Toğrul M. aut NATIONALLICENCE 700 1- Demirel N. aut NATIONALLICENCE 700 1- Hoşgören H. aut NATIONALLICENCE 773 0- Zeitschrift für Kristallographie - Crystalline Materials De Gruyter Oldenbourg 218/5(2003-05-01), 381-384 2194-4946 218:5<381 2003 218 zkri CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter