2D NMR Nutation Analysis of Non-Thermal Polarization of Coupled Multi-Spin Systems
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| 008 | 161128e20031201xx s 000 0 eng | ||
| 024 | 7 | 0 | |a 10.1524/zpch.217.12.1641.20479 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zpch.217.12.1641.20479 | ||
| 245 | 0 | 0 | |a 2D NMR Nutation Analysis of Non-Thermal Polarization of Coupled Multi-Spin Systems |h [Elektronische Daten] |c [K. L. Ivanov, K. Miesel, Hans-Martin Vieth, A. V. Yurkovskaya, R. Z. Sagdeev] |
| 520 | 3 | |a A new, convenient method of analyzing the spin polarization of a non-equilibrium system of N coupled nuclei is described and applied to photo-reactions exhibiting chemically induced dynamic nuclear polarization (CIDNP). It is based on the Fourier analysis of the variation of NMR line intensities as a function of the radio frequency excitation pulse length. A relationship between the spectral components at various harmonic order and the alignment in the spin multiplet is established. In application to the Norrish type I photolysis of cyclodecanone we demonstrate that at low magnetic field the rate determining step in the reaction kinetics depends on the mutual orientation of at least four pairs of non-equivalent spins. | |
| 540 | |a © 2003 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Thermodynamics & statistical physics |2 nationallicence | |
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Physical chemistry |2 nationallicence | |
| 700 | 1 | |a Ivanov |D K. L. |4 aut | |
| 700 | 1 | |a Miesel |D K. |4 aut | |
| 700 | 1 | |a Vieth |D Hans-Martin |4 aut | |
| 700 | 1 | |a Yurkovskaya |D A. V. |4 aut | |
| 700 | 1 | |a Sagdeev |D R. Z. |4 aut | |
| 773 | 0 | |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 217/12/2003(2003-12-01), 1641-1659 |x 0044-3336 |q 217:12/2003<1641 |1 2003 |2 217 |o zpch | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zpch.217.12.1641.20479 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zpch.217.12.1641.20479 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ivanov |D K. L. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Miesel |D K. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Vieth |D Hans-Martin |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Yurkovskaya |D A. V. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Sagdeev |D R. Z. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 217/12/2003(2003-12-01), 1641-1659 |x 0044-3336 |q 217:12/2003<1641 |1 2003 |2 217 |o zpch | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||