caa a22 4500 378862847 CHVBK 20180305123350.0 cr unu---uuuuu 161128e20031201xx s 000 0 eng 10.1524/zpch.217.12.1525.20482 doi (NATIONALLICENCE)gruyter-10.1524/zpch.217.12.1525.20482 Proton Transfer to Organometallic Hydrides via Unconventional Hydrogen Bonding: Problems and Perspectives [Elektronische Daten] [N. V. Belkova, E. I. Gutsul, E. S. Shubina, L. M. Epstein] This review summarizes the spectral and theoretical results concerning different ways of proton transfer through hydrogen bonds (HB) to metal atoms (XH···M) and hydride ligands (XH···HM) leading to classical and nonclassical cationic hydrides. The spectral (NMR, IR, UV-Vis in the temperature range 190-290K) and theoretical studies of the structural and energetic characteristics of HB intermediates and proton transfer allow the representation of the experimental energy profiles. The problems concerning the influence of different factors on the processes and potential energy surfaces requiring active investigations in this new area are discussed © 2003 Oldenbourg Wissenschaftsverlag GmbH Thermodynamics & statistical physics nationallicence Laboratory techniques, experiments nationallicence Physical chemistry nationallicence Belkova N. V. aut Gutsul E. I. aut Shubina E. S. aut Epstein L. M. aut Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 217/12/2003(2003-12-01), 1525-1538 0044-3336 217:12/2003<1525 2003 217 zpch https://doi.org/10.1524/zpch.217.12.1525.20482 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zpch.217.12.1525.20482 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Belkova N. V. aut NATIONALLICENCE 700 1- Gutsul E. I. aut NATIONALLICENCE 700 1- Shubina E. S. aut NATIONALLICENCE 700 1- Epstein L. M. aut NATIONALLICENCE 773 0- Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 217/12/2003(2003-12-01), 1525-1538 0044-3336 217:12/2003<1525 2003 217 zpch CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter