Synthesis of Monodisperse Heptanol Stabilized Ruthenium Nanoparticles. Evidence for the Presence of Surface Hydrogens

Verfasser / Beitragende:
[Katrin Pelzer, Karine Philippot, Bruno Chaudret]
Ort, Verlag, Jahr:
2003
Enthalten in:
Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics, 217/12/2003(2003-12-01), 1539-1548
Format:
Artikel (online)
ID: 378862863
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245 0 0 |a Synthesis of Monodisperse Heptanol Stabilized Ruthenium Nanoparticles. Evidence for the Presence of Surface Hydrogens  |h [Elektronische Daten]  |c [Katrin Pelzer, Karine Philippot, Bruno Chaudret] 
520 3 |a The decomposition of Ru(cod)(cot) (1; cod = 1,5-cyclooctadiene, cot = 1,3,5-cyclooctatriene) under an H2 atmosphere (3 bars) in pure heptanol produces crystalline monodisperse nanoparticles of 3nm mean size characterized by TEM and WAXS techniques. Solution NMR studies demonstrate the presence of surface hydrogens due to the synthesis process and suggest a fast exchange between free and coordinated heptanol molecules. 
540 |a © 2003 Oldenbourg Wissenschaftsverlag GmbH 
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