caa a22 4500 378862863 CHVBK 20180305123350.0 cr unu---uuuuu 161128e20031201xx s 000 0 eng 10.1524/zpch.217.12.1539.20474 doi (NATIONALLICENCE)gruyter-10.1524/zpch.217.12.1539.20474 Synthesis of Monodisperse Heptanol Stabilized Ruthenium Nanoparticles. Evidence for the Presence of Surface Hydrogens [Elektronische Daten] [Katrin Pelzer, Karine Philippot, Bruno Chaudret] The decomposition of Ru(cod)(cot) (1; cod = 1,5-cyclooctadiene, cot = 1,3,5-cyclooctatriene) under an H2 atmosphere (3 bars) in pure heptanol produces crystalline monodisperse nanoparticles of 3nm mean size characterized by TEM and WAXS techniques. Solution NMR studies demonstrate the presence of surface hydrogens due to the synthesis process and suggest a fast exchange between free and coordinated heptanol molecules. © 2003 Oldenbourg Wissenschaftsverlag GmbH Thermodynamics & statistical physics nationallicence Laboratory techniques, experiments nationallicence Physical chemistry nationallicence Pelzer Katrin aut Philippot Karine aut Chaudret Bruno aut Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 217/12/2003(2003-12-01), 1539-1548 0044-3336 217:12/2003<1539 2003 217 zpch https://doi.org/10.1524/zpch.217.12.1539.20474 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zpch.217.12.1539.20474 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Pelzer Katrin aut NATIONALLICENCE 700 1- Philippot Karine aut NATIONALLICENCE 700 1- Chaudret Bruno aut NATIONALLICENCE 773 0- Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 217/12/2003(2003-12-01), 1539-1548 0044-3336 217:12/2003<1539 2003 217 zpch CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter