The Influence of Secondary Chromophores on the Light Induced Oxidation of Paper Part I: The Influence of Light on Cellulose and Secondary Chromophores

Verfasser / Beitragende:
[Vladimír Bukovský, Mária Trnková]
Ort, Verlag, Jahr:
2003
Enthalten in:
Restaurator, 24/1(2003-03), 18-35
Format:
Artikel (online)
ID: 378863541
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024 7 0 |a 10.1515/REST.2003.18  |2 doi 
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245 0 4 |a The Influence of Secondary Chromophores on the Light Induced Oxidation of Paper Part I: The Influence of Light on Cellulose and Secondary Chromophores  |h [Elektronische Daten]  |c [Vladimír Bukovský, Mária Trnková] 
246 1 |a L'influence de chromophores secondaires sur l'oxydation du papier induite par la lumière. Première partie  |b L'influence de la lumière sur la cellulose et les chromophores secondaires 
520 3 |a The light induced oxidation of cellulose in pure cellulose is caused mainly by UV radiation and, to a lesser extent probably also by visible light (VIS). If some oxidation degradation products as formed in groundwood paper are present, the oxidation of cellulose caused by irradiation with daylight with a partly reduced UV component is sharply increased. This process occurs in a neutral or acidic environment; it is the result of mainly visible light action. It is possible that it refers to an activation of cellulose oxidation in the course of the light induced oxidation degradation of chromophores in a bleaching process. The chromophores lose this activation effect by shifting to an alkaline pH, i.e. by deacidification, in this study done by the methanolic MMC method. Chromophores themselves are submitted to significant light induced oxidation degradation under the influence of visible light, which results in the bleaching of the paper. A UV filter considerably limits the light induced oxidation of cellulose, but does not stop the degradation of the chromophores. 
540 |a © 2003 K. G. Saur Verlag GmbH, Ortlerstr. 8, D-81373 München 
700 1 |a Bukovský  |D Vladimír  |u Slovak National Library, Preservation Service Branch, Nám. J.C. Hronského 1, 036 01 Martin, Slovak Republic. E-mail: bukovsky@snk.sk  |4 aut 
700 1 |a Trnková  |D Mária  |u Slovak National Library, Preservation Service Branch, Nám. J.C. Hronského 1, 036 01 Martin, Slovak Republic. E-mail: trnkova@.snk.sk  |4 aut 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Trnková  |D Mária  |u Slovak National Library, Preservation Service Branch, Nám. J.C. Hronského 1, 036 01 Martin, Slovak Republic. E-mail: trnkova@.snk.sk  |4 aut 
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