caa a22 4500 378865951 CHVBK 20180305123357.0 cr unu---uuuuu 161128e20030101xx s 000 0 eng 10.1351/pac200375060801 doi (NATIONALLICENCE)gruyter-10.1351/pac200375060801 Critical review of analytical applications of Mössbauer spectroscopy illustrated by mineralogical and geological examples (IUPAC Technical Report) [Elektronische Daten] [E. Kuzmann, S. Nagy, A. Vértes] We have developed a new terminology for Mössbauer pattern analysis in order to enhance the performance of qualitative analysis by Mössbauer spectroscopy. In this approach, Mössbauer parameters are considered as a function of a number of externally adjusted experimental parameters at which the spectrum has been recorded. The basis of analytical classification is the microenvironment, which is determined by an assembly of atoms causing the same hyperfine interactions at one particular class of the Mössbauer probe atoms.Since Mössbauer spectroscopy measures hyperfine interactions very sensitively, the microenvironment presents itself as a fundamental concept for analytical purposes. Our approach can also help to systematize the Mössbauer data for the identification of individual physicochemical species from the corresponding patterns present in the spectrum. © 2013 Walter de Gruyter GmbH, Berlin/Boston Kuzmann E. aut Nagy S. aut Vértes A. aut Pure and Applied Chemistry De Gruyter 75/6(2003-01-01), 801-858 0033-4545 75:6<801 2003 75 pac https://doi.org/10.1351/pac200375060801 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1351/pac200375060801 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kuzmann E. aut NATIONALLICENCE 700 1- Nagy S. aut NATIONALLICENCE 700 1- Vértes A. aut NATIONALLICENCE 773 0- Pure and Applied Chemistry De Gruyter 75/6(2003-01-01), 801-858 0033-4545 75:6<801 2003 75 pac CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter