Chemoenzymatic methods for the enantioselective preparation of sesquiterpenoid natural products from aromatic precursors

Verfasser / Beitragende:
[M. G. Banwell, A. J. Edwards, G. J. Harfoot, K. A. Jolliffe, M. D. McLeod, K. J. McRae, S. G. Stewart, M. Vögtle]
Ort, Verlag, Jahr:
2003
Enthalten in:
Pure and Applied Chemistry, 75/2-3(2003-01-01), 223-229
Format:
Artikel (online)
ID: 37886629X
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245 0 0 |a Chemoenzymatic methods for the enantioselective preparation of sesquiterpenoid natural products from aromatic precursors  |h [Elektronische Daten]  |c [M. G. Banwell, A. J. Edwards, G. J. Harfoot, K. A. Jolliffe, M. D. McLeod, K. J. McRae, S. G. Stewart, M. Vögtle] 
520 3 |a The enantiomerically pure cis-1,2-dihydrocatechols 2, which are generated by enzymatic dihydroxylation of the corresponding aromatic, engage in regio- and stereo-controlled Diels-Alder cycloaddition reactions to give a range of synthetically useful bicyclo[2.2.2]octenes. Certain examples of the latter type of compound have been used as starting materials in the synthesis of the sesquiterpenoids (−)-patchoulenone and (−)-hirsutene. 
540 |a © 2013 Walter de Gruyter GmbH, Berlin/Boston 
700 1 |a Banwell  |D M. G.  |u Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia  |4 aut 
700 1 |a Edwards  |D A. J.  |u Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia  |4 aut 
700 1 |a Harfoot  |D G. J.  |u Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia  |4 aut 
700 1 |a Jolliffe  |D K. A.  |u Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia  |4 aut 
700 1 |a McLeod  |D M. D.  |u Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia  |4 aut 
700 1 |a McRae  |D K. J.  |u Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia  |4 aut 
700 1 |a Stewart  |D S. G.  |u Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia  |4 aut 
700 1 |a Vögtle  |D M.  |u Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia  |4 aut 
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