caa a22 4500 37886629X CHVBK 20180305123358.0 cr unu---uuuuu 161128e20030101xx s 000 0 eng 10.1351/pac200375020223 doi (NATIONALLICENCE)gruyter-10.1351/pac200375020223 Chemoenzymatic methods for the enantioselective preparation of sesquiterpenoid natural products from aromatic precursors [Elektronische Daten] [M. G. Banwell, A. J. Edwards, G. J. Harfoot, K. A. Jolliffe, M. D. McLeod, K. J. McRae, S. G. Stewart, M. Vögtle] The enantiomerically pure cis-1,2-dihydrocatechols 2, which are generated by enzymatic dihydroxylation of the corresponding aromatic, engage in regio- and stereo-controlled Diels-Alder cycloaddition reactions to give a range of synthetically useful bicyclo[2.2.2]octenes. Certain examples of the latter type of compound have been used as starting materials in the synthesis of the sesquiterpenoids (−)-patchoulenone and (−)-hirsutene. © 2013 Walter de Gruyter GmbH, Berlin/Boston Banwell M. G. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut Edwards A. J. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut Harfoot G. J. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut Jolliffe K. A. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut McLeod M. D. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut McRae K. J. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut Stewart S. G. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut Vögtle M. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut Pure and Applied Chemistry De Gruyter 75/2-3(2003-01-01), 223-229 0033-4545 75:2-3<223 2003 75 pac https://doi.org/10.1351/pac200375020223 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1351/pac200375020223 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Banwell M. G. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut NATIONALLICENCE 700 1- Edwards A. J. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut NATIONALLICENCE 700 1- Harfoot G. J. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut NATIONALLICENCE 700 1- Jolliffe K. A. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut NATIONALLICENCE 700 1- McLeod M. D. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut NATIONALLICENCE 700 1- McRae K. J. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut NATIONALLICENCE 700 1- Stewart S. G. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut NATIONALLICENCE 700 1- Vögtle M. Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, ACT 0200, Australia aut NATIONALLICENCE 773 0- Pure and Applied Chemistry De Gruyter 75/2-3(2003-01-01), 223-229 0033-4545 75:2-3<223 2003 75 pac CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter