Microencapsulated methylrhenium trioxide (MTO)/H2O2 systems for the oxidation of cardanol derivatives

Verfasser / Beitragende:
[R. Saladino, E. Mincione, O. A. Attanasi, Paolino Filippone]
Ort, Verlag, Jahr:
2003
Enthalten in:
Pure and Applied Chemistry, 75/2-3(2003-01-01), 265-272
Format:
Artikel (online)
ID: 378866338
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245 0 0 |a Microencapsulated methylrhenium trioxide (MTO)/H2O2 systems for the oxidation of cardanol derivatives  |h [Elektronische Daten]  |c [R. Saladino, E. Mincione, O. A. Attanasi, Paolino Filippone] 
520 3 |a A convenient and efficient application of microencapsulated/methylrhenium trioxide (MTO) and MTO/pyridine systems for the selective oxidation of cardanol derivatives is reported. Environmentally friendly and low-cost H2O2 was used as the oxygen atom donor. The catalysts were stable systems for at least five recycling experiments. In the oxidation of C2 alkyl-substituted cardanol derivatives, high conversion and yields of the corresponding para-benzoquinones were obtained. By contrast, in the absence of the C2 substituent, an unprecedented oxidative degradation to di-γ-lactone derivative was observed. 
540 |a © 2013 Walter de Gruyter GmbH, Berlin/Boston 
700 1 |a Saladino  |D R.  |u Dipartimento di Agrobiologia ed Agrochimica, Unità INFM, Università della Tuscia, Via S. Camillo de Lellis, 01100 Viterbo, Italy  |4 aut 
700 1 |a Mincione  |D E.  |u Dipartimento di Agrobiologia ed Agrochimica, Unità INFM, Università della Tuscia, Via S. Camillo de Lellis, 01100 Viterbo, Italy  |4 aut 
700 1 |a Attanasi  |D O. A.  |u Centro di Studio delle Sostanze Naturali, Università di Urbino, 61029 Urbino, Italy  |4 aut 
700 1 |a Filippone  |D Paolino  |u Centro di Studio delle Sostanze Naturali, Università di Urbino, 61029 Urbino, Italy  |4 aut 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Mincione  |D E.  |u Dipartimento di Agrobiologia ed Agrochimica, Unità INFM, Università della Tuscia, Via S. Camillo de Lellis, 01100 Viterbo, Italy  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Attanasi  |D O. A.  |u Centro di Studio delle Sostanze Naturali, Università di Urbino, 61029 Urbino, Italy  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Filippone  |D Paolino  |u Centro di Studio delle Sostanze Naturali, Università di Urbino, 61029 Urbino, Italy  |4 aut 
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