caa a22 4500 378866338 CHVBK 20180305123358.0 cr unu---uuuuu 161128e20030101xx s 000 0 eng 10.1351/pac200375020265 doi (NATIONALLICENCE)gruyter-10.1351/pac200375020265 Microencapsulated methylrhenium trioxide (MTO)/H2O2 systems for the oxidation of cardanol derivatives [Elektronische Daten] [R. Saladino, E. Mincione, O. A. Attanasi, Paolino Filippone] A convenient and efficient application of microencapsulated/methylrhenium trioxide (MTO) and MTO/pyridine systems for the selective oxidation of cardanol derivatives is reported. Environmentally friendly and low-cost H2O2 was used as the oxygen atom donor. The catalysts were stable systems for at least five recycling experiments. In the oxidation of C2 alkyl-substituted cardanol derivatives, high conversion and yields of the corresponding para-benzoquinones were obtained. By contrast, in the absence of the C2 substituent, an unprecedented oxidative degradation to di-γ-lactone derivative was observed. © 2013 Walter de Gruyter GmbH, Berlin/Boston Saladino R. Dipartimento di Agrobiologia ed Agrochimica, Unità INFM, Università della Tuscia, Via S. Camillo de Lellis, 01100 Viterbo, Italy aut Mincione E. Dipartimento di Agrobiologia ed Agrochimica, Unità INFM, Università della Tuscia, Via S. Camillo de Lellis, 01100 Viterbo, Italy aut Attanasi O. A. Centro di Studio delle Sostanze Naturali, Università di Urbino, 61029 Urbino, Italy aut Filippone Paolino Centro di Studio delle Sostanze Naturali, Università di Urbino, 61029 Urbino, Italy aut Pure and Applied Chemistry De Gruyter 75/2-3(2003-01-01), 265-272 0033-4545 75:2-3<265 2003 75 pac https://doi.org/10.1351/pac200375020265 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1351/pac200375020265 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Saladino R. Dipartimento di Agrobiologia ed Agrochimica, Unità INFM, Università della Tuscia, Via S. Camillo de Lellis, 01100 Viterbo, Italy aut NATIONALLICENCE 700 1- Mincione E. Dipartimento di Agrobiologia ed Agrochimica, Unità INFM, Università della Tuscia, Via S. Camillo de Lellis, 01100 Viterbo, Italy aut NATIONALLICENCE 700 1- Attanasi O. A. Centro di Studio delle Sostanze Naturali, Università di Urbino, 61029 Urbino, Italy aut NATIONALLICENCE 700 1- Filippone Paolino Centro di Studio delle Sostanze Naturali, Università di Urbino, 61029 Urbino, Italy aut NATIONALLICENCE 773 0- Pure and Applied Chemistry De Gruyter 75/2-3(2003-01-01), 265-272 0033-4545 75:2-3<265 2003 75 pac CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter