Multitracer studies on the permeation of rare earth elements through a supported liquid membrane containing 2-ethylhexyl phosphonic acid-2-ethylhexyl ester (EHEHPA)
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| 024 | 7 | 0 | |a 10.1524/ract.91.4.217.19965 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/ract.91.4.217.19965 | ||
| 245 | 0 | 0 | |a Multitracer studies on the permeation of rare earth elements through a supported liquid membrane containing 2-ethylhexyl phosphonic acid-2-ethylhexyl ester (EHEHPA) |h [Elektronische Daten] |c [Shizuko Ambe, Daisuke Abe, Takuo Ozaki, Fumitoshi Ambe] |
| 520 | 3 | |a The simultaneous permeation of Sc, Y, Ce, Pm, Eu, Gd, Yb and Lu through a 2-ethylhexyl phosphonic acid-2-ethylhexyl ester (EHEHPA)-decalin membrane supported on a microporous polytetrafluoroethylene sheet was studied using a multitracer. The permeation rates of the elements from feed solutions of various acidity into receiving solutions of 2mol dm-3 HCl were determined. The feed solution at pH 1.5 gave the highest percentage of permeation for Ce, Pm, Eu, Gd and Yb, amounting to about 90 after -25h permeation. The percentage of permeation of Y and Lu was the highest at pH 1, amounting to about 90 after -25h permeation. The permeation of Sc from all the feed solutions was less than 4 due to its adsorption on the vessel. The permeation from the feed solution at pH 1.5 into the receiving solutions of 1, 2, 3, 4 and 5mol dm-3 HCl showed that the maximum percentage of transport for Y and Yb was obtained in 2mol dm-3 HCl receiving solution and that for Lu in 2-4mol dm-3 HCl receiving solutions. The other elements gave a percentage of transport more than 90 in 1-5mol dm-3 HCl receiving solutions, showing no obvious HCl concentration effect. The permeability coefficients of these elements were determined. Solvent extraction of the elements by EHEHPA-decalin was also carried out for comparison. | |
| 540 | |a © 2003 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Analytical chemistry |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 700 | 1 | |a Ambe |D Shizuko |4 aut | |
| 700 | 1 | |a Abe |D Daisuke |4 aut | |
| 700 | 1 | |a Ozaki |D Takuo |4 aut | |
| 700 | 1 | |a Ambe |D Fumitoshi |4 aut | |
| 773 | 0 | |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 91/4/2003(2003-04-01), 217-222 |x 0033-8230 |q 91:4/2003<217 |1 2003 |2 91 |o ract | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/ract.91.4.217.19965 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/ract.91.4.217.19965 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ambe |D Shizuko |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Abe |D Daisuke |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ozaki |D Takuo |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ambe |D Fumitoshi |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 91/4/2003(2003-04-01), 217-222 |x 0033-8230 |q 91:4/2003<217 |1 2003 |2 91 |o ract | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||