Salt Effects on Reactivity for Substitution Reactions of Pentacyanoferrate(II) Complexes
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| 024 | 7 | 0 | |a 10.1515/irm-2003-0107 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1515/irm-2003-0107 | ||
| 245 | 0 | 0 | |a Salt Effects on Reactivity for Substitution Reactions of Pentacyanoferrate(II) Complexes |h [Elektronische Daten] |c [Saad Alshehri, John Burgess] |
| 520 | 3 | |a Rate constants are reported for ligand replacement in three pentacyanoferrate(III) complexes [Fe(CN)5L]3- with L = 4-cyanopyridine, 4,4'-bipyridyl, or 4-t-butyl-pyridine, in a range of aqueous salt solutions. These salts include chlorides and bromides of potassium, lithium, and calcium, and tetra-alkyl-ammonium bromides, at concentrations within the range 0.50 and 2.00 mol dm-3. The observed trends are compared with those for a selection of other inorganic reactions. | |
| 540 | |a © 2014 by Walter de Gruyter Berlin/Boston | ||
| 690 | 7 | |a Iron (II) complexes |2 nationallicence | |
| 690 | 7 | |a pentacyanoferrate (II) |2 nationallicence | |
| 690 | 7 | |a salt effects |2 nationallicence | |
| 690 | 7 | |a substitution rates |2 nationallicence | |
| 700 | 1 | |a Alshehri |D Saad |4 aut | |
| 700 | 1 | |a Burgess |D John |4 aut | |
| 773 | 0 | |t BioInorganic Reaction Mechanisms |d De Gruyter |g 5/1(2003-01-01), 59-64 |x 2191-2483 |q 5:1<59 |1 2003 |2 5 |o irm | |
| 856 | 4 | 0 | |u https://doi.org/10.1515/irm-2003-0107 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1515/irm-2003-0107 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Alshehri |D Saad |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Burgess |D John |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t BioInorganic Reaction Mechanisms |d De Gruyter |g 5/1(2003-01-01), 59-64 |x 2191-2483 |q 5:1<59 |1 2003 |2 5 |o irm | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
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| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||