Synthesis, Characterisation and Dissociation of a Glycinate Bridged Trinuclear Co(III)-Cu(II)-Co(III) Complex

Verfasser / Beitragende:
[Ν. N. Das, A. Dash, G. S. Brahama, P. Mohanty]
Ort, Verlag, Jahr:
2003
Enthalten in:
BioInorganic Reaction Mechanisms, 5/1(2003-01-01), 73-78
Format:
Artikel (online)
ID: 378871137
LEADER caa a22 4500
001 378871137
003 CHVBK
005 20180305123409.0
007 cr unu---uuuuu
008 161128e20030101xx s 000 0 eng
024 7 0 |a 10.1515/irm-2003-0109  |2 doi 
035 |a (NATIONALLICENCE)gruyter-10.1515/irm-2003-0109 
245 0 0 |a Synthesis, Characterisation and Dissociation of a Glycinate Bridged Trinuclear Co(III)-Cu(II)-Co(III) Complex  |h [Elektronische Daten]  |c [Ν. N. Das, A. Dash, G. S. Brahama, P. Mohanty] 
520 3 |a A trinuclear complex, [{(NH3)5Co(O2CCH2NH)}2Cu](ClO4)6.2H2O has been synthesised using mononuclear glycinato(pentaammine)cobalt(III) Perchlorate and characterised by various physicochemical methods. The kinetic study by stopped-flow spectrophotometer indicated that the dissociation of the trinuclear complex occurred mainly through an acid catalysed path. 
540 |a © 2014 by Walter de Gruyter Berlin/Boston 
690 7 |a cobalt(III)  |2 nationallicence 
690 7 |a copper(II)  |2 nationallicence 
690 7 |a glycinate  |2 nationallicence 
690 7 |a trinuclear complex  |2 nationallicence 
690 7 |a dissociation kinetics  |2 nationallicence 
700 1 |a Das  |D Ν. N.  |4 aut 
700 1 |a Dash  |D A.  |4 aut 
700 1 |a Brahama  |D G. S.  |4 aut 
700 1 |a Mohanty  |D P.  |4 aut 
773 0 |t BioInorganic Reaction Mechanisms  |d De Gruyter  |g 5/1(2003-01-01), 73-78  |x 2191-2483  |q 5:1<73  |1 2003  |2 5  |o irm 
856 4 0 |u https://doi.org/10.1515/irm-2003-0109  |q text/html  |z Onlinezugriff via DOI 
908 |D 1  |a research article  |2 jats 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1515/irm-2003-0109  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Das  |D Ν. N.  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Dash  |D A.  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Brahama  |D G. S.  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Mohanty  |D P.  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t BioInorganic Reaction Mechanisms  |d De Gruyter  |g 5/1(2003-01-01), 73-78  |x 2191-2483  |q 5:1<73  |1 2003  |2 5  |o irm 
900 7 |b CC0  |u http://creativecommons.org/publicdomain/zero/1.0  |2 nationallicence 
898 |a BK010053  |b XK010053  |c XK010000 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-gruyter