Kinetic and mechanistic studies of mono(terpyridine)- to bis(terpyridine)-nickel(II) complex formation reactions involving a range of substituted 2,2′:6′,2″-terpyridine ligands: an investigation of π-stacking interactions in outer-sphere complexes
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| 024 | 7 | 0 | |a 10.1515/irm-2003-0103 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1515/irm-2003-0103 | ||
| 245 | 0 | 0 | |a Kinetic and mechanistic studies of mono(terpyridine)- to bis(terpyridine)-nickel(II) complex formation reactions involving a range of substituted 2,2′:6′,2″-terpyridine ligands: an investigation of π-stacking interactions in outer-sphere complexes |h [Elektronische Daten] |c [Gleb U. Priimov, Peter Moore] |
| 520 | 3 | |a Using a range of substituted 2,2':6',2"-terpyridine ligands, the effects of π-stacking on the rates of formation of bis(terpyridine)nickel(II) complexes have been investigated in 70:30 v/v % methanol:water. Compared with the rates of formation of the mono(terpyridine)nickel(II) complexes, for the bis(terpyridine)nickel(II) complexes at 25°C, rate enhancements in the range 11-146 were found. For unsubstituted 2,2':6',2"-terpyridine studied in the same solvent mixture, the rate enhancement at 25°C is 11, whereas for 4'-(2-naphthyl)-2,2':6',2"-terpyridine the rate enhancement is 146. | |
| 540 | |a © 2014 by Walter de Gruyter Berlin/Boston | ||
| 700 | 1 | |a Priimov |D Gleb U. |4 aut | |
| 700 | 1 | |a Moore |D Peter |4 aut | |
| 773 | 0 | |t BioInorganic Reaction Mechanisms |d De Gruyter |g 5/1(2003-01-01), 21-30 |x 2191-2483 |q 5:1<21 |1 2003 |2 5 |o irm | |
| 856 | 4 | 0 | |u https://doi.org/10.1515/irm-2003-0103 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1515/irm-2003-0103 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Priimov |D Gleb U. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Moore |D Peter |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t BioInorganic Reaction Mechanisms |d De Gruyter |g 5/1(2003-01-01), 21-30 |x 2191-2483 |q 5:1<21 |1 2003 |2 5 |o irm | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||