caa a22 4500 378872192 CHVBK 20180305123411.0 cr unu---uuuuu 161128e20031101xx s 000 0 eng 10.1524/ract.91.11.633.23473 doi (NATIONALLICENCE)gruyter-10.1524/ract.91.11.633.23473 Bion Lionel BASSIST: an applied thermodynamic database for radionuclide chemistry [Elektronische Daten] [Lionel Bion] BASSIST (Base Applied to Speciation in Solution, at Interfaces and SolubiliTy) is an applied thermodynamic database (TDB) for chemistry of long-lived radionuclides. This TDB is developed at the French Atomic Energy Commission (CEA) and concerns solution, sorption and dissolution equilibria. The order of the different steps necessary to elaborate this TDB are presented, from a critical review of experimental acquisitions until to a database compilation. Important concepts such as the heterogeneity of data, the coherence of database and the use of chemical analogies between elements are discussed by using an example of application of the TDB in speciation calculation. The TDB BASSIST is built by using "certified" data, such as selected values of the Nuclear Energy Agency (NEA) and some uncertified data from literature. In the last part of this article, the choice of chemical analogies between elements, the impact of different sets of data on uranium(IV) speciation calculations are discussed. © 2003 Oldenbourg Wissenschaftsverlag GmbH Laboratory techniques, experiments nationallicence Analytical chemistry nationallicence Inorganic chemistry nationallicence Radiochimica Acta/International journal for chemical aspects of nuclear science and technology Oldenbourg Wissenschaftsverlag GmbH 91/11/2003(2003-11-01), 633-638 0033-8230 91:11/2003<633 2003 91 ract https://doi.org/10.1524/ract.91.11.633.23473 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/ract.91.11.633.23473 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Bion Lionel NATIONALLICENCE 773 0- Radiochimica Acta/International journal for chemical aspects of nuclear science and technology Oldenbourg Wissenschaftsverlag GmbH 91/11/2003(2003-11-01), 633-638 0033-8230 91:11/2003<633 2003 91 ract CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter