Actinide speciation in the environment

Verfasser / Beitragende:
[Gregory R. Choppin]
Ort, Verlag, Jahr:
2003
Enthalten in:
Radiochimica Acta/International journal for chemical aspects of nuclear science and technology, 91/11/2003(2003-11-01), 645-650
Format:
Artikel (online)
ID: 378872206
LEADER caa a22 4500
001 378872206
003 CHVBK
005 20180305123411.0
007 cr unu---uuuuu
008 161128e20031101xx s 000 0 eng
024 7 0 |a 10.1524/ract.91.11.645.23469  |2 doi 
035 |a (NATIONALLICENCE)gruyter-10.1524/ract.91.11.645.23469 
100 1 |a Choppin  |D Gregory R. 
245 1 0 |a Actinide speciation in the environment  |h [Elektronische Daten]  |c [Gregory R. Choppin] 
520 3 |a The chemical behavior of the actinide elements in the environment depends upon their oxidation state and chemical species. Plutonium is the major transuranic element in the environment due to releases in nuclear weapons testing. The major factors influencing environmental behavior of plutonium, including redox, compexation, colloid formation, solubility, etc. are discussed. The strong hydrolysis and low solubility of Pu(OH)4 limits the solubility concentrations of plutonium in the other, more soluble oxidation states and results in plutonium in environmental waters being mainly present in colloids. To perform valid modeling, it is necessary to have reliable knowledge on the nature of plutonium present, the oxidation state (or states) and reliable stability constants for the complexes which may be formed in these oxidation states. These problems and possible approaches to their solution are the main focus of this paper. 
540 |a © 2003 Oldenbourg Wissenschaftsverlag GmbH 
690 7 |a Laboratory techniques, experiments  |2 nationallicence 
690 7 |a Analytical chemistry  |2 nationallicence 
690 7 |a Inorganic chemistry  |2 nationallicence 
773 0 |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology  |d Oldenbourg Wissenschaftsverlag GmbH  |g 91/11/2003(2003-11-01), 645-650  |x 0033-8230  |q 91:11/2003<645  |1 2003  |2 91  |o ract 
856 4 0 |u https://doi.org/10.1524/ract.91.11.645.23469  |q text/html  |z Onlinezugriff via DOI 
908 |D 1  |a research article  |2 jats 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1524/ract.91.11.645.23469  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 100  |E 1-  |a Choppin  |D Gregory R. 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology  |d Oldenbourg Wissenschaftsverlag GmbH  |g 91/11/2003(2003-11-01), 645-650  |x 0033-8230  |q 91:11/2003<645  |1 2003  |2 91  |o ract 
900 7 |b CC0  |u http://creativecommons.org/publicdomain/zero/1.0  |2 nationallicence 
898 |a BK010053  |b XK010053  |c XK010000 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-gruyter