Evaluation of the Structures of Polysaccharides from Two New Zealand Members of the Ceramiaceae

Verfasser / Beitragende:
[I. J. Miller]
Ort, Verlag, Jahr:
2003
Enthalten in:
Botanica Marina, 46/4(2003-07-07), 378-385
Format:
Artikel (online)
ID: 378872516
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100 1 |a Miller  |D I. J. 
245 1 0 |a Evaluation of the Structures of Polysaccharides from Two New Zealand Members of the Ceramiaceae  |h [Elektronische Daten]  |c [I. J. Miller] 
520 3 |a The structures of the polysaccharides extracted from Griffithsia antarctica and Ceramium uncinatum, both from the family Ceramiaceae (order Ceramiales) were evaluated. Both were based on the agar structure with a high level of precursors. The polysaccharide from Griffithsia antarctica was almost completely sulfated at the 4-position, with approximately half the 4-linked units either anhydrogalactose or its precursor (in about equal amounts comparing the sugar analysis with the linkage analysis), and the other half sulfated at the 3-position and, additionally, with 2-xylosyl, 2-sulfate or 6-sulfate ester as substituents. The polysaccharide from Ceramium uncinatum was somewhat different in nature. One in four of the 3-linked units was sulfated at the 6-position, while half of the 4-linked units were in the anhydrogalactosyl form, with approximately equal amounts of galactose, galactose 6-sulfate (anhydrogalactose precursor) and galactose substituted with xylose making up the remaining 4-linked units. Both polysaccharides showed low levels of 6-O-methylgalactose and 2-O-methyl-3,6-anhydrogalactose. 
540 |a Copyright © 2003 by Walter de Gruyter GmbH & Co. KG 
690 7 |a Hydrobiology  |2 nationallicence 
690 7 |a Mycology, fungi  |2 nationallicence 
690 7 |a Botany & plant sciences  |2 nationallicence 
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