The Chemical Structure of Galactans from Sarcodia montagneana and from Sarcodia flabellata

Verfasser / Beitragende:
[I. J. Miller]
Ort, Verlag, Jahr:
2003
Enthalten in:
Botanica Marina, 46/4(2003-07-07), 392-399
Format:
Artikel (online)
ID: 378872540
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245 1 4 |a The Chemical Structure of Galactans from Sarcodia montagneana and from Sarcodia flabellata  |h [Elektronische Daten]  |c [I. J. Miller] 
520 3 |a The polysaccharides from Sarcodia montagneana and from Sarcodia flabellata were examined by 13C NMR spectroscopy. Analysis of these spectra showed the 3-linked D-galactosyl units were mostly substituted at the 2-position by sulfate ester, and at the 4,6-position by pyruvate acetal. The 4-linked galactosyl units were almost entirely in the L-configuration, the 3-position was almost entirely substituted by sulfate ester, and a high percentage of these were substituted at the 2-position by sulfate ester. However, there was also a significant fraction of the 4-linked units with 2,3,6-trisubstitution by sulfate ester, and these units appeared to be linked to 3-linked units substituted with 2-sulfate ester and pyruvate, that is, these diads had no non-substituted hydroxyl group. A previous report that Sarcodia polysaccharides are equivalent to λ-carrageenan is wrong, but the polysaccharide is similar to the polysaccharides previously isolated from Trematocarpus species, confirming an association suggested previously on the basis of gene sequencing. 
540 |a Copyright © 2003 by Walter de Gruyter GmbH & Co. KG 
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