caa a22 4500 378873768 CHVBK 20180305123415.0 cr unu---uuuuu 161128e20031101xx s 000 0 eng 10.1524/zpch.217.11.1369.20484 doi (NATIONALLICENCE)gruyter-10.1524/zpch.217.11.1369.20484 Eftekhari Ali Electrochemical Behavior and Enhanced Stability of a Thin Film of Prussian Blue Deposited under Magnetic Field [Elektronische Daten] [Ali Eftekhari] Magnetic field was employed as a useful tool to improve stability of electroactive films deposited on substrate surfaces. To this aim, electrochemical preparation/deposition of Prussian blue (PB) was carried out in the presence of an external magnetic field to form a thin film onto a Pt substrate electrode. The results were compared with a conventional PB modified electrode throughout the research. For the electrode prepared in the presence of the magnetic field, a stronger voltammetric behavior with higher peak current was observed. It was accompanied by higher chemical and electrochemical stabilities of the deposited electroactive film. Spectroscopic measurements were also performed to investigate the influence of the applied magnetic film on the properties of the electroactive film deposited. The results were indicative of the fact that deposition under magnetic filed is accompanied by stronger chemical bonds and different elemental composition of the electroactive material formed on the electrode surface. Based on the experimental results, it was concluded that both Lorentz and magnetic forces are responsible for the behavior observed. © 2003 Oldenbourg Wissenschaftsverlag GmbH Thermodynamics & statistical physics nationallicence Laboratory techniques, experiments nationallicence Physical chemistry nationallicence Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 217/11/2003(2003-11-01), 1369-1386 0044-3336 217:11/2003<1369 2003 217 zpch https://doi.org/10.1524/zpch.217.11.1369.20484 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zpch.217.11.1369.20484 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Eftekhari Ali NATIONALLICENCE 773 0- Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 217/11/2003(2003-11-01), 1369-1386 0044-3336 217:11/2003<1369 2003 217 zpch CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter