caa a22 4500 378874144 CHVBK 20180305123416.0 cr unu---uuuuu 161128e20030801xx s 000 0 eng 10.1524/ract.91.8.449.20008 doi (NATIONALLICENCE)gruyter-10.1524/ract.91.8.449.20008 Temperature dependence and effect of oxide anion on the americium chemistry in the molten LiCl-KCl eutectic [Elektronische Daten] [David Lambertin, Sylvie Sanchez, Gérard S. Picard, Jérôme Lacquement] The chemical properties of americium chlorides have been studied in the fused eutectic LiCl-KCl as a function of temperature ranging from 743K to 943K. Titration of Am(III) chlorocomplex by O2- demonstrated the existence of soluble AmO+ species as well as the precipitation of AmOCl and Am2O3 solid compounds. The corresponding solubility products of AmOCl and Am2O3 have been determined. Calculated Am(II) disproportionation equilibrium constant indicates that the stability of Am(II) chlorocomplex increases with the increase of temperature. © 2003 Oldenbourg Wissenschaftsverlag GmbH Laboratory techniques, experiments nationallicence Analytical chemistry nationallicence Inorganic chemistry nationallicence Lambertin David aut Sanchez Sylvie aut Picard Gérard S. aut Lacquement Jérôme aut Radiochimica Acta/International journal for chemical aspects of nuclear science and technology Oldenbourg Wissenschaftsverlag GmbH 91/8/2003(2003-08-01), 449-452 0033-8230 91:8/2003<449 2003 91 ract https://doi.org/10.1524/ract.91.8.449.20008 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/ract.91.8.449.20008 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Lambertin David aut NATIONALLICENCE 700 1- Sanchez Sylvie aut NATIONALLICENCE 700 1- Picard Gérard S. aut NATIONALLICENCE 700 1- Lacquement Jérôme aut NATIONALLICENCE 773 0- Radiochimica Acta/International journal for chemical aspects of nuclear science and technology Oldenbourg Wissenschaftsverlag GmbH 91/8/2003(2003-08-01), 449-452 0033-8230 91:8/2003<449 2003 91 ract CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter