Limiting transport properties of lanthanide and actinide ions in pure water

Verfasser / Beitragende:
[E. Mauerhofer, K. P. Zhernosekov, Frank Rösch]
Ort, Verlag, Jahr:
2003
Enthalten in:
Radiochimica Acta/International journal for chemical aspects of nuclear science and technology, 91/8/2003(2003-08-01), 473-478
Format:
Artikel (online)
ID: 378874160
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024 7 0 |a 10.1524/ract.91.8.473.20009  |2 doi 
035 |a (NATIONALLICENCE)gruyter-10.1524/ract.91.8.473.20009 
245 0 0 |a Limiting transport properties of lanthanide and actinide ions in pure water  |h [Elektronische Daten]  |c [E. Mauerhofer, K. P. Zhernosekov, Frank Rösch] 
520 3 |a The limiting transport properties, i.e. the limiting ionic conductivity (λ°) and the limiting diffusion coefficient (D°), of lanthanide and actinide ions at 298.15K have been calculated by means of the microscopic version of the Stokes-Einstein law involving (i) the effective charge and the ionic radius of the ions and (ii) the ion micro-viscosity, i.e. the viscosity of the hydrated water molecules in the vicinity of the ion. The latter quantity was derived from the variation of the dynamic properties of the water molecules in the first hydration shell with the surface charge density of common mono-atomic cations of various charges. The obtained results were found to be consistent with the experimental data given in the literature. 
540 |a © 2003 Oldenbourg Wissenschaftsverlag GmbH 
690 7 |a Laboratory techniques, experiments  |2 nationallicence 
690 7 |a Analytical chemistry  |2 nationallicence 
690 7 |a Inorganic chemistry  |2 nationallicence 
700 1 |a Mauerhofer  |D E.  |4 aut 
700 1 |a Zhernosekov  |D K. P.  |4 aut 
700 1 |a Rösch  |D Frank  |4 aut 
773 0 |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology  |d Oldenbourg Wissenschaftsverlag GmbH  |g 91/8/2003(2003-08-01), 473-478  |x 0033-8230  |q 91:8/2003<473  |1 2003  |2 91  |o ract 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Zhernosekov  |D K. P.  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Rösch  |D Frank  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology  |d Oldenbourg Wissenschaftsverlag GmbH  |g 91/8/2003(2003-08-01), 473-478  |x 0033-8230  |q 91:8/2003<473  |1 2003  |2 91  |o ract 
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