caa a22 4500 378874160 CHVBK 20180305123416.0 cr unu---uuuuu 161128e20030801xx s 000 0 eng 10.1524/ract.91.8.473.20009 doi (NATIONALLICENCE)gruyter-10.1524/ract.91.8.473.20009 Limiting transport properties of lanthanide and actinide ions in pure water [Elektronische Daten] [E. Mauerhofer, K. P. Zhernosekov, Frank Rösch] The limiting transport properties, i.e. the limiting ionic conductivity (λ°) and the limiting diffusion coefficient (D°), of lanthanide and actinide ions at 298.15K have been calculated by means of the microscopic version of the Stokes-Einstein law involving (i) the effective charge and the ionic radius of the ions and (ii) the ion micro-viscosity, i.e. the viscosity of the hydrated water molecules in the vicinity of the ion. The latter quantity was derived from the variation of the dynamic properties of the water molecules in the first hydration shell with the surface charge density of common mono-atomic cations of various charges. The obtained results were found to be consistent with the experimental data given in the literature. © 2003 Oldenbourg Wissenschaftsverlag GmbH Laboratory techniques, experiments nationallicence Analytical chemistry nationallicence Inorganic chemistry nationallicence Mauerhofer E. aut Zhernosekov K. P. aut Rösch Frank aut Radiochimica Acta/International journal for chemical aspects of nuclear science and technology Oldenbourg Wissenschaftsverlag GmbH 91/8/2003(2003-08-01), 473-478 0033-8230 91:8/2003<473 2003 91 ract https://doi.org/10.1524/ract.91.8.473.20009 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/ract.91.8.473.20009 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mauerhofer E. aut NATIONALLICENCE 700 1- Zhernosekov K. P. aut NATIONALLICENCE 700 1- Rösch Frank aut NATIONALLICENCE 773 0- Radiochimica Acta/International journal for chemical aspects of nuclear science and technology Oldenbourg Wissenschaftsverlag GmbH 91/8/2003(2003-08-01), 473-478 0033-8230 91:8/2003<473 2003 91 ract CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter