Determination of Mo(VI), Ru(III), Re(VII) and NO3- in the solutions of nuclear fuel cycle by capillary electrophoresis
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| 024 | 7 | 0 | |a 10.1524/ract.91.8.479.20003 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/ract.91.8.479.20003 | ||
| 245 | 0 | 0 | |a Determination of Mo(VI), Ru(III), Re(VII) and NO3- in the solutions of nuclear fuel cycle by capillary electrophoresis |h [Elektronische Daten] |c [B. Fourest, A. Maslennikov, F. David, M. Masson] |
| 520 | 3 | |a A method for simultaneous quantitative determination of Mo(VI), Re(VII), Ru(III) and NO3- ions in aqueous solutions, using capillary zone electrophoresis (CZE) technique with direct UV detection, was developed. Electrophoretic mobility of Ru(III) ions in 0.1M NaHCO3 solution was determined as 6.0×10-8m2 V-1 s-1 at 25 °C. The best analytical characteristics of the developed method were achieved with a 100mM carbonate buffer solution containing 0.3mM TTAB, at a pH value of 9.8 and at an applied voltage of 10kV. Under these conditions, a linear relationship between the measured absorbance (λ=230nm) and the concentration of the species under study were observed in the range 5×10-6-10-3M for Mo(VI), 7×10-6-10-3M for Re(VII) and 10-5--4M for Ru(III). The minimum detectable concentrations were determined as 4.1×10-6M for NO3-, 5.2×10-6M for Mo(VI), 7.4×10-6M for Re(VII) and 1.0×10-5M for Ru(III). The accuracy of quantitative determination was estimated as 3%-5% for NO3- and 5%-6% for Mo(VI), Re(VII) and Ru(III) ions. The presence of 0.06M NaNO3 (HNO3) and of 10-3M U(VI) in the sample affected neither the detection limits of the species under study nor the selectivity of the method. | |
| 540 | |a © 2003 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Analytical chemistry |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 700 | 1 | |a Fourest |D B. |4 aut | |
| 700 | 1 | |a Maslennikov |D A. |4 aut | |
| 700 | 1 | |a David |D F. |4 aut | |
| 700 | 1 | |a Masson |D M. |4 aut | |
| 773 | 0 | |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 91/8/2003(2003-08-01), 479-486 |x 0033-8230 |q 91:8/2003<479 |1 2003 |2 91 |o ract | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/ract.91.8.479.20003 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/ract.91.8.479.20003 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Fourest |D B. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Maslennikov |D A. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a David |D F. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Masson |D M. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 91/8/2003(2003-08-01), 479-486 |x 0033-8230 |q 91:8/2003<479 |1 2003 |2 91 |o ract | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||