The crystal structures of the potassium hydrogen monofluorophosphates, KHPO3F and K3[H(PO3F)2], and the α modification of RbHPO3F
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| 024 | 7 | 0 | |a 10.1524/zkri.218.9.604.20681 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.218.9.604.20681 | ||
| 245 | 0 | 4 | |a The crystal structures of the potassium hydrogen monofluorophosphates, KHPO3F and K3[H(PO3F)2], and the α modification of RbHPO3F |h [Elektronische Daten] |c [Hillary A. Prescott, Sergej I. Troyanov, Erhard Kemnitz] |
| 520 | 3 | |a Three new hydrogen monofluorophosphates, KHPO3F (I), K3[H(PO3F)2] (II), and α-RbHPO3F (III), were crystallographically characterized with single crystal X-ray analysis at 180 K. The compound I is monoclinic, space group P21 with a = 7.273(1), b = 14.086(3), c = 7.655(2) Å, β = 90.13(3), Z = 8, and R1 and wR2 factors of 0.0214 and 0.0395, respectively. II crystallizes in the monoclinic space group C2/c with a = 7.973(3), b = 11.635(4), c = 9.688(4) Å, β = 113.52(4), Z = 4, and R1 and wR2 factors of 0.0581 and 0.1615, respectively. III is monoclinic with the P21/n space group, a = 7.465(2), b = 15.551(8), c = 7.563(4) Å, β = 105.38(5), Z = 8, and R1 and wR2 factors of 0.0365 and 0.0694, respectively. I and III include O-H···O hydrogen bonding between the HPO3F tetrahedra to form branched spiral chains (I) or tetramers (III), respectively. In the structure of II, dimeric units are formed by a symmetrically disordered hydrogen bond between the PO3F tetrahedra. Both O and F atoms participate in cation coordination in all three structures, whereas only O atoms are involved in hydrogen bonding. | |
| 540 | |a © 2003 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Prescott |D Hillary A. |4 aut | |
| 700 | 1 | |a Troyanov |D Sergej I. |4 aut | |
| 700 | 1 | |a Kemnitz |D Erhard |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 218/9(2003-09-01), 604-611 |x 2194-4946 |q 218:9<604 |1 2003 |2 218 |o zkri | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zkri.218.9.604.20681 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.218.9.604.20681 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Prescott |D Hillary A. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Troyanov |D Sergej I. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kemnitz |D Erhard |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 218/9(2003-09-01), 604-611 |x 2194-4946 |q 218:9<604 |1 2003 |2 218 |o zkri | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||