Dichloro[(E)-2-chloro-1-vinyl-cyclohexanol](4-methoxy phenyl)Te(IV). A case of conformational polymorphism

Verfasser / Beitragende:
[Maurício Vega Teijido, Julio Zukerman-Schpector, Robinson Luis Camillo, Ignez Caracelli, Hélio Alexandre Stefani, André Chieffi, João Valdir Comasseto]
Ort, Verlag, Jahr:
2003
Enthalten in:
Zeitschrift für Kristallographie - Crystalline Materials, 218/9(2003-09-01), 636-641
Format:
Artikel (online)
ID: 378877755
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245 0 0 |a Dichloro[(E)-2-chloro-1-vinyl-cyclohexanol](4-methoxy phenyl)Te(IV). A case of conformational polymorphism  |h [Elektronische Daten]  |c [Maurício Vega Teijido, Julio Zukerman-Schpector, Robinson Luis Camillo, Ignez Caracelli, Hélio Alexandre Stefani, André Chieffi, João Valdir Comasseto] 
520 3 |a C15Cl3H19O2Te, Mr = 465.25, (1), P21/a, a = 9.8303(9), b = 17.492(2), c = 10.911(1) Å, β = 108.521(8)°, Z = 4, R1 = 0.0274. (2), P21/c, a = 8.2661(9), b = 22.863(2), c = 9.828(1) Å, β = 108.894(8)°, Z = 4, R1 = 0.0379. In both compounds, the primary geometry of the TeIV atom is a pseudo-trigonal-bipyramidal arrangement with two halide atoms in apical positions and a lone pair of electrons and C atoms in the equatorial plane. In (1), the TeIV atom is involved in an intermolecular secondary interaction resulting in the self-assembly of a chain-like supramolecular array. In (2), molecules are linked in centrosymmetric dimers through Cl···H-O interactions. 
540 |a © 2003 Oldenbourg Wissenschaftsverlag GmbH 
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