caa a22 4500 378877755 CHVBK 20180305123424.0 cr unu---uuuuu 161128e20030901xx s 000 0 eng 10.1524/zkri.218.9.636.20679 doi (NATIONALLICENCE)gruyter-10.1524/zkri.218.9.636.20679 Dichloro[(E)-2-chloro-1-vinyl-cyclohexanol](4-methoxy phenyl)Te(IV). A case of conformational polymorphism [Elektronische Daten] [Maurício Vega Teijido, Julio Zukerman-Schpector, Robinson Luis Camillo, Ignez Caracelli, Hélio Alexandre Stefani, André Chieffi, João Valdir Comasseto] C15Cl3H19O2Te, Mr = 465.25, (1), P21/a, a = 9.8303(9), b = 17.492(2), c = 10.911(1) Å, β = 108.521(8)°, Z = 4, R1 = 0.0274. (2), P21/c, a = 8.2661(9), b = 22.863(2), c = 9.828(1) Å, β = 108.894(8)°, Z = 4, R1 = 0.0379. In both compounds, the primary geometry of the TeIV atom is a pseudo-trigonal-bipyramidal arrangement with two halide atoms in apical positions and a lone pair of electrons and C atoms in the equatorial plane. In (1), the TeIV atom is involved in an intermolecular secondary interaction resulting in the self-assembly of a chain-like supramolecular array. In (2), molecules are linked in centrosymmetric dimers through Cl···H-O interactions. © 2003 Oldenbourg Wissenschaftsverlag GmbH Crystallography nationallicence Inorganic chemistry nationallicence Organic chemistry nationallicence Teijido Maurício Vega aut Zukerman-Schpector Julio aut Camillo Robinson Luis aut Caracelli Ignez aut Stefani Hélio Alexandre aut Chieffi André aut Comasseto João Valdir aut Zeitschrift für Kristallographie - Crystalline Materials De Gruyter Oldenbourg 218/9(2003-09-01), 636-641 2194-4946 218:9<636 2003 218 zkri https://doi.org/10.1524/zkri.218.9.636.20679 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zkri.218.9.636.20679 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Teijido Maurício Vega aut NATIONALLICENCE 700 1- Zukerman-Schpector Julio aut NATIONALLICENCE 700 1- Camillo Robinson Luis aut NATIONALLICENCE 700 1- Caracelli Ignez aut NATIONALLICENCE 700 1- Stefani Hélio Alexandre aut NATIONALLICENCE 700 1- Chieffi André aut NATIONALLICENCE 700 1- Comasseto João Valdir aut NATIONALLICENCE 773 0- Zeitschrift für Kristallographie - Crystalline Materials De Gruyter Oldenbourg 218/9(2003-09-01), 636-641 2194-4946 218:9<636 2003 218 zkri CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter