Crystal structure of the K, Ti analogue of ilímaussite-(Ce), (Ba,K,Na,Ca)11-12(REE,Fe,Th)4(Ti,Nb)6(Si6O18)4(OH)12·4.5 H2O: revision of structure model and structural formula
Gespeichert in:
Verfasser / Beitragende:
[Sergey V. Krivovichev, V. N. Yakovenchuk, Th. Armbruster, Y. A. Pakhomovskiy, W. Depmeier]
Ort, Verlag, Jahr:
2003
Enthalten in:
Zeitschrift für Kristallographie - Crystalline Materials, 218/6(2003-06-01), 392-396
Format:
Artikel (online)
Online Zugang:
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| 024 | 7 | 0 | |a 10.1524/zkri.218.6.392.20721 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.218.6.392.20721 | ||
| 245 | 0 | 0 | |a Crystal structure of the K, Ti analogue of ilímaussite-(Ce), (Ba,K,Na,Ca)11-12(REE,Fe,Th)4(Ti,Nb)6(Si6O18)4(OH)12·4.5 H2O: revision of structure model and structural formula |h [Elektronische Daten] |c [Sergey V. Krivovichev, V. N. Yakovenchuk, Th. Armbruster, Y. A. Pakhomovskiy, W. Depmeier] |
| 520 | 3 | |a The crystal structure of the K, Ti analogue of il¡maussite-(Ce), (Ba,K,Na,Ca)11-12(REE,Fe,Th)4(Ti,Nb)6(Si6O18)4(OH)12·4.5 H2O, from the Yukspor mountain, Khibiny massif, Kola peninsula, Russia, has been solved by direct methods and refined to R1 = 0.077 on the basis of 1762 reflections with |Fo| ≥ 4σF. The mineral is rhombohedral, R32, a = 10.708(2), c = 60.073(11) Å, V = 5965.2(17) Å3. The structure is based upon a heteropolyhedral framework that consists of layers of corner-linked polyhedra. The SiO4 tetrahedra share corners to form 6-membered rings which are further interlinked via REEO6 trigonal prisms and Tiφ6 octahedra (φ = O, OH). The obtained structure model is different from that recently reported by Rastsvetaeva et al. (2003) which is considered incorrect. | |
| 540 | |a © 2003 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Krivovichev |D Sergey V. |4 aut | |
| 700 | 1 | |a Yakovenchuk |D V. N. |4 aut | |
| 700 | 1 | |a Armbruster |D Th |4 aut | |
| 700 | 1 | |a Pakhomovskiy |D Y. A. |4 aut | |
| 700 | 1 | |a Depmeier |D W. |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 218/6(2003-06-01), 392-396 |x 2194-4946 |q 218:6<392 |1 2003 |2 218 |o zkri | |
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| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.218.6.392.20721 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Krivovichev |D Sergey V. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Yakovenchuk |D V. N. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Armbruster |D Th |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Pakhomovskiy |D Y. A. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Depmeier |D W. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 218/6(2003-06-01), 392-396 |x 2194-4946 |q 218:6<392 |1 2003 |2 218 |o zkri | ||
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