Thermodynamic modeling of metal-ligand interactions in high ionic strength NaCl solutions: the Ni2+-oxalate system
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| 024 | 7 | 0 | |a 10.1524/ract.91.3.169.19978 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/ract.91.3.169.19978 | ||
| 245 | 0 | 0 | |a Thermodynamic modeling of metal-ligand interactions in high ionic strength NaCl solutions: the Ni2+-oxalate system |h [Elektronische Daten] |c [M. Borkowski, Gregory R. Choppin, Robert C. Moore] |
| 520 | 3 | |a Stability constants for the 1:1 and 1:2 complexes of Ni(II)+Oxalate have been determined using solvent extraction. Data collected in 0.3m to 5.0m NaCl aqueous solutions at 20.0±0.1°C yielded values of log β101 ranging from 3.71 to 3.98(±0.06) and of log β102 from 6.44 to 6.95(±0.06), which agree well with values from the literature. The data were analyzed by the Pitzer model with a value of μ0/RT=-17.47 for the 1:1 complex calculated from the data and literature values. A single neutral-ion interaction parameter λNiOx-Cl=-0.179 was used to describe the ionic strength dependence of the 1:1 complex. For the 1:2 complex, a value for μ0/RT=-11.31 and the Pitzer parameters values, β0NiOx₂²⁻-Na⁺=-0.0644 and β1NiOx₂²⁻-Na⁺=0.8545, were determined. These standard chemical potential values are based on a model for oxalate deprotonation reported earlier. | |
| 540 | |a © 2003 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Analytical chemistry |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 700 | 1 | |a Borkowski |D M. |4 aut | |
| 700 | 1 | |a Choppin |D Gregory R. |4 aut | |
| 700 | 1 | |a Moore |D Robert C. |4 aut | |
| 773 | 0 | |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 91/3/2003(2003-03-01), 169-172 |x 0033-8230 |q 91:3/2003<169 |1 2003 |2 91 |o ract | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/ract.91.3.169.19978 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/ract.91.3.169.19978 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Borkowski |D M. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Choppin |D Gregory R. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Moore |D Robert C. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 91/3/2003(2003-03-01), 169-172 |x 0033-8230 |q 91:3/2003<169 |1 2003 |2 91 |o ract | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 986 | |a SWISSBIB |b 378608169 | ||
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||