Thermochromatographic studies of berkelium chlorides: BkCl3 and BkCl4
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| 024 | 7 | 0 | |a 10.1524/ract.91.3.123.19975 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/ract.91.3.123.19975 | ||
| 245 | 0 | 0 | |a Thermochromatographic studies of berkelium chlorides: BkCl3 and BkCl4 |h [Elektronische Daten] |c [Alexander B. Yakushev, B. Eichler, A. Türler, H.W. Gäggeler, J. Peterson] |
| 520 | 3 | |a The thermochromatographic behavior of berkelium chlorides in various chlorinating gases was studied. Using Cl2 or a mixture of Cl2/SOCl2, two peaks were observed in a thermochromatographic column. The "high temperature" peak corresponds to BkCl3 and the "low temperature" one corresponds most probably to BkCl4. Using both the model of mobile adsorption and the of Monte Carlo method, the adsorption enthalpies were determined. The possible chemical reactions in a chromatographic column are discussed. | |
| 540 | |a © 2003 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Analytical chemistry |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 700 | 1 | |a Yakushev |D Alexander B. |4 aut | |
| 700 | 1 | |a Eichler |D B. |4 aut | |
| 700 | 1 | |a Türler |D A. |4 aut | |
| 700 | 1 | |a Gäggeler |D H.W. |4 aut | |
| 700 | 1 | |a Peterson |D J. |4 aut | |
| 773 | 0 | |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 91/3/2003(2003-03-01), 123-126 |x 0033-8230 |q 91:3/2003<123 |1 2003 |2 91 |o ract | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/ract.91.3.123.19975 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/ract.91.3.123.19975 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Yakushev |D Alexander B. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Eichler |D B. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Türler |D A. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Gäggeler |D H.W. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Peterson |D J. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 91/3/2003(2003-03-01), 123-126 |x 0033-8230 |q 91:3/2003<123 |1 2003 |2 91 |o ract | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||