The correlation between metal oxidation state and bond valence parameters for M—O bonds (M
V, Fe and Cu). A simple method to search for the metal oxidation-state independent parameter pairs
| LEADER | caa a22 4500 | ||
|---|---|---|---|
| 001 | 378883895 | ||
| 003 | CHVBK | ||
| 005 | 20180305123438.0 | ||
| 007 | cr unu---uuuuu | ||
| 008 | 161128e20041001xx s 000 0 eng | ||
| 024 | 7 | 0 | |a 10.1524/zkri.219.10.614.50820 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.219.10.614.50820 | ||
| 245 | 0 | 4 | |a The correlation between metal oxidation state and bond valence parameters for M—O bonds (M |h [Elektronische Daten] |b V, Fe and Cu). A simple method to search for the metal oxidation-state independent parameter pairs |c [Sheng-Zhi Hu, Zhao-Hui Zhou] |
| 520 | 3 | |a Based on the latest available crystal data and the reported bond valence parameters, the linear correlation between the bond valence parameter R0 with B = 0.37 Å for M—O bonds (M = V, Fe and Cu) and the metal oxidation state n is shown for the first time. For V—O bonds, a linear equation of R0 ∼ n is perfectly established as R0 = 0.0250n + 1.674 (n = 2-5). Similarly, a linear equation for Fe—O bonds is fitted as R0 = 0.0335n + 1.648 (n = 2-4), as well as R0 = 0.0855n + 1.482 (n = 1-3) for Cu—O bonds fitted properly. In addition, the linear correlation between R0 and n within certain range of B values for V—O and Fe—O bonds is also established. Consequently, the oxidation-state independent parameters (R0, B) of (1.788, 0.32 Å) for V—O bonds and (1.795, 0.30 Å) for Fe—O bonds can be derived from the zero slope of the R0 ∼ n straight lines. However, a similar parameter pair for Cu—O bonds cannot be found using this unique approach. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Hu |D Sheng-Zhi |4 aut | |
| 700 | 1 | |a Zhou |D Zhao-Hui |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/10(2004-10-01), 614-620 |x 2194-4946 |q 219:10<614 |1 2004 |2 219 |o zkri | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zkri.219.10.614.50820 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.219.10.614.50820 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Hu |D Sheng-Zhi |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Zhou |D Zhao-Hui |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/10(2004-10-01), 614-620 |x 2194-4946 |q 219:10<614 |1 2004 |2 219 |o zkri | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||