Triphenylphosphine adducts of silver di-iso-propyl dithiophosphate
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| 024 | 7 | 0 | |a 10.1524/zkri.219.10.664.50823 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.219.10.664.50823 | ||
| 245 | 0 | 0 | |a Triphenylphosphine adducts of silver di-iso-propyl dithiophosphate |h [Elektronische Daten] |c [Yihui Huang, Edward R. T. Tiekink] |
| 520 | 3 | |a The molecular structure of dimeric {[S2P(OiPr)2](PPh3)}2 · 2 CHCl3 is built up about a centrosymmetric eight-membered ring that adopts a chair conformation as a result of bidentate bridging dithiophos phate ligands. The silver atom is in a trigonal planar geometry. Relatively close transannular Ag S interactions are noted which, if considered significant, leads to a tridentate dithiophosphate ligand and a distorted tetrahedral geometry for silver. The presence of two PPh3 molecules in the coordination sphere of silver in monomeric Ag[S2P(OiPr)2](PPh3)2 · 3 CHCl3 as well as a bidentate di thiophosphate ligand gives rise to a tetrahedral geometry. Adducts with lower or greater numbers of PPh3 ligands could not be obtained pointing to the inherent stability of the characterised structures. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Huang |D Yihui |4 aut | |
| 700 | 1 | |a Tiekink |D Edward R. T. |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/10(2004-10-01), 664-668 |x 2194-4946 |q 219:10<664 |1 2004 |2 219 |o zkri | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zkri.219.10.664.50823 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.219.10.664.50823 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Huang |D Yihui |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Tiekink |D Edward R. T. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/10(2004-10-01), 664-668 |x 2194-4946 |q 219:10<664 |1 2004 |2 219 |o zkri | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||