caa a22 4500 378886479 CHVBK 20180305123444.0 cr unu---uuuuu 161128e20040701xx s 000 0 eng 10.1524/zpch.218.7.803.35726 doi (NATIONALLICENCE)gruyter-10.1524/zpch.218.7.803.35726 Comparison of the Macroscopic Molecular Properties in Understanding the Structural Aspects of Mixed Aquo-Organic Binary Mixtures [Elektronische Daten] [Dilip Kumar Kuila, S. C. Lahiri] Understanding the structural aspects of aquo + organic mixtures and finding out a suitable physico-chemical parameter as a structural probe is of great importance from a theoretical and experimental point of view. Attempts have been made to derive useful relations regarding the structure of aquo + organic mixtures [ethylene glycol + water, glycerol + water, dioxane + water, acetone + water and acetonitrile + water mixtures] of widely divergent characteristics based on different macroscopic molecular properties: (i)excess thermodynamic properties of mixing, (ii)excess dielectric constants, (iii)excess polarizability volumes, (iii)correlation factor ‘g', (v)ultrasonic sound absorption, (vi)basicity or other suitable expressions. The properties give valuable details regarding the structure of aquo + organic mixtures. Macroscopic molecular properties provide a summary of all interaction energies over a long time, but finer structural details may be available from microscopic properties (using relaxation techniques etc.). A comparison of the macroscopic and microscopic methods for the determination of structural aspects of solvent systems is presented. © 2004 Oldenbourg Wissenschaftsverlag GmbH Thermodynamics & statistical physics nationallicence Laboratory techniques, experiments nationallicence Physical chemistry nationallicence Kuila Dilip Kumar aut Lahiri S. C. aut Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/7/2004(2004-07-01), 803-828 0942-9352 218:7/2004<803 2004 218 zpch https://doi.org/10.1524/zpch.218.7.803.35726 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zpch.218.7.803.35726 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kuila Dilip Kumar aut NATIONALLICENCE 700 1- Lahiri S. C. aut NATIONALLICENCE 773 0- Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/7/2004(2004-07-01), 803-828 0942-9352 218:7/2004<803 2004 218 zpch CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter