An Ideal-Like Quinary Aqueous Solution Equilibrated with a Solid Cadmium-Containing Complex
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| 024 | 7 | 0 | |a 10.1524/zpch.218.7.881.35730 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zpch.218.7.881.35730 | ||
| 245 | 0 | 3 | |a An Ideal-Like Quinary Aqueous Solution Equilibrated with a Solid Cadmium-Containing Complex |h [Elektronische Daten] |c [Jun Wang, Zhi-Chang Wang] |
| 520 | 3 | |a Complex-containing solutions such as H2O-NaCl-CdCl2 always strongly deviate from ideality and the non-ideality often increases with the complex former concentrations. Here we report isopiestic measurements of the H2O-NaCl-CdCl2-mannitol-sorbitol quinary solution equilibrated with the 2NaCl · CdCl2 · 3H2O solid complex at 25°C, which show a linear relation between mannitol and sorbitol molalities, similar to that for the H2O-mannitol-sorbitol ternary solution. The reason for the ideal-like behavior of the quinary solution is that the saturated complex 2NaCl · CdCl2 · 3H2O has the similar effects as the isopiestic water on the unsaturated solutes mannitol and sorbitol and that the interaction between the isomers mannitol and sorbitol is negligible. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Thermodynamics & statistical physics |2 nationallicence | |
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Physical chemistry |2 nationallicence | |
| 700 | 1 | |a Wang |D Jun |4 aut | |
| 700 | 1 | |a Wang |D Zhi-Chang |4 aut | |
| 773 | 0 | |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/7/2004(2004-07-01), 881-885 |x 0942-9352 |q 218:7/2004<881 |1 2004 |2 218 |o zpch | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zpch.218.7.881.35730 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zpch.218.7.881.35730 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Wang |D Jun |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Wang |D Zhi-Chang |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/7/2004(2004-07-01), 881-885 |x 0942-9352 |q 218:7/2004<881 |1 2004 |2 218 |o zpch | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||