caa a22 4500 378886495 CHVBK 20180305123444.0 cr unu---uuuuu 161128e20040701xx s 000 0 eng 10.1524/zpch.218.7.881.35730 doi (NATIONALLICENCE)gruyter-10.1524/zpch.218.7.881.35730 An Ideal-Like Quinary Aqueous Solution Equilibrated with a Solid Cadmium-Containing Complex [Elektronische Daten] [Jun Wang, Zhi-Chang Wang] Complex-containing solutions such as H2O-NaCl-CdCl2 always strongly deviate from ideality and the non-ideality often increases with the complex former concentrations. Here we report isopiestic measurements of the H2O-NaCl-CdCl2-mannitol-sorbitol quinary solution equilibrated with the 2NaCl · CdCl2 · 3H2O solid complex at 25°C, which show a linear relation between mannitol and sorbitol molalities, similar to that for the H2O-mannitol-sorbitol ternary solution. The reason for the ideal-like behavior of the quinary solution is that the saturated complex 2NaCl · CdCl2 · 3H2O has the similar effects as the isopiestic water on the unsaturated solutes mannitol and sorbitol and that the interaction between the isomers mannitol and sorbitol is negligible. © 2004 Oldenbourg Wissenschaftsverlag GmbH Thermodynamics & statistical physics nationallicence Laboratory techniques, experiments nationallicence Physical chemistry nationallicence Wang Jun aut Wang Zhi-Chang aut Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/7/2004(2004-07-01), 881-885 0942-9352 218:7/2004<881 2004 218 zpch https://doi.org/10.1524/zpch.218.7.881.35730 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zpch.218.7.881.35730 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Jun aut NATIONALLICENCE 700 1- Wang Zhi-Chang aut NATIONALLICENCE 773 0- Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/7/2004(2004-07-01), 881-885 0942-9352 218:7/2004<881 2004 218 zpch CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter