Electrochemical Lithium Insertion/Extraction in Partially Reduced α-MoO3
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| 024 | 7 | 0 | |a 10.1524/zpch.218.11.1259.50809 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zpch.218.11.1259.50809 | ||
| 245 | 0 | 0 | |a Electrochemical Lithium Insertion/Extraction in Partially Reduced α-MoO3 |h [Elektronische Daten] |c [A. M. Hashem, H. Abbas, A. E. Abdel-Ghany] |
| 520 | 3 | |a This work concerns with synthesis, structural, thermal and electrochemical characterization of molybdenum oxides (stoichiometric MoO3, sub-stoichiometric oxide MoO3−x (where x is a small fraction) with layered type structure. XRD investigations of the samples proved that the crystal structure of the layered α-MoO3) has been maintained after the reduction process. The reduced samples exhibited a drastically improved charge/discharge cycling stability and capacity retention on cycling in 1M LiClO4/propylene carbonate. At higher cycle numbers (approx. cycle 50) the discharge capacity of the reduced molybdenum oxides stabilizes at a level of approx. 50mAhg−1, whereas the non-reduced MoO3 has retained only about 45mAhg−1 after 20 cycles. This significant improvement of the rechargeability may be related to improvement in the electronic conductivity after reduction process. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Thermodynamics & statistical physics |2 nationallicence | |
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Physical chemistry |2 nationallicence | |
| 700 | 1 | |a Hashem |D A. M. |4 aut | |
| 700 | 1 | |a Abbas |D H. |4 aut | |
| 700 | 1 | |a Abdel-Ghany |D A. E. |4 aut | |
| 773 | 0 | |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/11/2004(2004-11-01), 1259-1272 |x 0942-9352 |q 218:11/2004<1259 |1 2004 |2 218 |o zpch | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zpch.218.11.1259.50809 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zpch.218.11.1259.50809 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Hashem |D A. M. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Abbas |D H. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Abdel-Ghany |D A. E. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/11/2004(2004-11-01), 1259-1272 |x 0942-9352 |q 218:11/2004<1259 |1 2004 |2 218 |o zpch | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||