caa a22 4500 378891855 CHVBK 20180305123456.0 cr unu---uuuuu 161128e20041101xx s 000 0 eng 10.1524/zpch.218.11.1231.50812 doi (NATIONALLICENCE)gruyter-10.1524/zpch.218.11.1231.50812 Koop Thomas Homogeneous Ice Nucleation in Water and Aqueous Solutions [Elektronische Daten] [Thomas Koop] This review provides an introduction to ice nucleation processes in supercooled water and aqueous solutions. Concepts for experimental techniques suitable to study homogeneous ice nucleation are addressed, in particular differential scanning calorimetry of inverse emulsions. Ice nucleation data from aqueous solutions have been analyzed using two approaches, and the interrelations between those are examined. It is argued that the ice nucleation process is driven entirely by thermodynamic quantities and how this can be understood in the context of three proposed theories for supercooled liquid water. Ice nucleation data for pure water droplets surrounded by a gas have been compiled and evaluated; within experimental uncertainty neither a volume dependent nucleation process nor a surface dependent nucleation process is convincingly supported by the analysis. Finally, open questions in the area of supercooled aqueous solutions and ice nucleation are discussed. © 2004 Oldenbourg Wissenschaftsverlag GmbH Thermodynamics & statistical physics nationallicence Laboratory techniques, experiments nationallicence Physical chemistry nationallicence Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/11/2004(2004-11-01), 1231-1258 0942-9352 218:11/2004<1231 2004 218 zpch https://doi.org/10.1524/zpch.218.11.1231.50812 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zpch.218.11.1231.50812 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Koop Thomas NATIONALLICENCE 773 0- Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/11/2004(2004-11-01), 1231-1258 0942-9352 218:11/2004<1231 2004 218 zpch CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter