Reduction kinetics of Np(VI) by n-butyraldehyde in tributyl phosphate diluted with n-dodecane
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| 024 | 7 | 0 | |a 10.1524/ract.92.12.883.55113 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/ract.92.12.883.55113 | ||
| 245 | 0 | 0 | |a Reduction kinetics of Np(VI) by n-butyraldehyde in tributyl phosphate diluted with n-dodecane |h [Elektronische Daten] |c [Yasutoshi Ban, Toshihide Asakura, Yasuji Morita] |
| 520 | 3 | |a The reduction kinetics of Np(VI) by n-butyraldehyde in 30% TBP solution diluted with n-dodecane were analyzed by spectrophotometry. Based on the results of both n-butyraldehyde and nitric acid concentration dependences on the Np(VI) reduction reaction, the rate equation was obtained as -d[Np(VI)]/dt=k[n-C3H7CHO]0.8[HNO3]-2.0[Np(VI)]t where k=(1.0±0.2)× 10-3M1.2 min-1 at 294±1K. The activation energy of the reaction was 76±5kJ/mol. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Analytical chemistry |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 700 | 1 | |a Ban |D Yasutoshi |4 aut | |
| 700 | 1 | |a Asakura |D Toshihide |4 aut | |
| 700 | 1 | |a Morita |D Yasuji |4 aut | |
| 773 | 0 | |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 92/12/2004(2004-12-01), 883-887 |x 0033-8230 |q 92:12/2004<883 |1 2004 |2 92 |o ract | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/ract.92.12.883.55113 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/ract.92.12.883.55113 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ban |D Yasutoshi |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Asakura |D Toshihide |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Morita |D Yasuji |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 92/12/2004(2004-12-01), 883-887 |x 0033-8230 |q 92:12/2004<883 |1 2004 |2 92 |o ract | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||