Solvation of poly(methyl acrylate) and poly(vinyl acetate) by CO2 studied via atomistic Monte Carlo simulation techniques
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| 024 | 7 | 0 | |a 10.1515/epoly.2004.4.1.13 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1515/epoly.2004.4.1.13 | ||
| 245 | 0 | 0 | |a Solvation of poly(methyl acrylate) and poly(vinyl acetate) by CO2 studied via atomistic Monte Carlo simulation techniques |h [Elektronische Daten] |c [Sabine Beuermann, Michael Buback, Marco Drache, Dorit Nelke, Gudrun Schmidt-Naake] |
| 520 | 3 | |a The differences in solubility of poly(vinyl acetate) (PVAc) and poly(methyl acrylate) (PMA) were addressed by applying atomistic Monte Carlo simulation techniques. Polymer segments consisting of nine monomer units serve as model compounds for polymer chains. As a measure of intermolecular interactions with the solvent environment, cohesion energies of the polymer segments embedded in either the corresponding monomer or in CO2 were calculated. Only in case of PMA segments in CO2 environment, specific interactions between polymer segments were identified. This finding is in agreement with experimental results on phase behaviour and propagation kinetics. | |
| 540 | |a © 2013 by Walter de Gruyter GmbH & Co. | ||
| 700 | 1 | |a Beuermann |D Sabine |u Georg-August Universität Göttingen, Institut für Physikalische Chemie, Tammannstraße 6, 37077 Göttingen, Germany |4 aut | |
| 700 | 1 | |a Buback |D Michael |u Georg-August Universität Göttingen, Institut für Physikalische Chemie, Tammannstraße 6, 37077 Göttingen, Germany |4 aut | |
| 700 | 1 | |a Drache |D Marco |u Technische Universität Clausthal, Institut für Technische Chemie, Erzstraße 18, 38678 Clausthal-Zellerfeld, Germany |4 aut | |
| 700 | 1 | |a Nelke |D Dorit |u Georg-August Universität Göttingen, Institut für Physikalische Chemie, Tammannstraße 6, 37077 Göttingen, Germany |4 aut | |
| 700 | 1 | |a Schmidt-Naake |D Gudrun |u Technische Universität Clausthal, Institut für Technische Chemie, Erzstraße 18, 38678 Clausthal-Zellerfeld, Germany |4 aut | |
| 773 | 0 | |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 13-19 |x 2197-4586 |q 4:1<13 |1 2004 |2 4 |o epoly | |
| 856 | 4 | 0 | |u https://doi.org/10.1515/epoly.2004.4.1.13 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1515/epoly.2004.4.1.13 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Beuermann |D Sabine |u Georg-August Universität Göttingen, Institut für Physikalische Chemie, Tammannstraße 6, 37077 Göttingen, Germany |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Buback |D Michael |u Georg-August Universität Göttingen, Institut für Physikalische Chemie, Tammannstraße 6, 37077 Göttingen, Germany |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Drache |D Marco |u Technische Universität Clausthal, Institut für Technische Chemie, Erzstraße 18, 38678 Clausthal-Zellerfeld, Germany |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Nelke |D Dorit |u Georg-August Universität Göttingen, Institut für Physikalische Chemie, Tammannstraße 6, 37077 Göttingen, Germany |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Schmidt-Naake |D Gudrun |u Technische Universität Clausthal, Institut für Technische Chemie, Erzstraße 18, 38678 Clausthal-Zellerfeld, Germany |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 13-19 |x 2197-4586 |q 4:1<13 |1 2004 |2 4 |o epoly | ||
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| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||