Synthesis and electrooptical characterization of polysiloxanes containing indolyl groups acting as photoconductive substrates for photorefractive materials

Verfasser / Beitragende:
[Rocco Angelone, Claudia Castè, Valter Castelvetro, Francesco Ciardelli, Arturo Colligiani, Francesco Greco, Alessandro Mazzotta, Giacomo Ruggeri]
Ort, Verlag, Jahr:
2004
Enthalten in:
e-Polymers, 4/1(2004-12-01), 863-877
Format:
Artikel (online)
ID: 378903144
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024 7 0 |a 10.1515/epoly.2004.4.1.863  |2 doi 
035 |a (NATIONALLICENCE)gruyter-10.1515/epoly.2004.4.1.863 
245 0 0 |a Synthesis and electrooptical characterization of polysiloxanes containing indolyl groups acting as photoconductive substrates for photorefractive materials  |h [Elektronische Daten]  |c [Rocco Angelone, Claudia Castè, Valter Castelvetro, Francesco Ciardelli, Arturo Colligiani, Francesco Greco, Alessandro Mazzotta, Giacomo Ruggeri] 
520 3 |a Synthesis and electrooptical analysis of polysiloxane and poly-N-vinyl derivatives containing indolyl groups are reported. The indole group and some of its methyl derivatives have been taken into account in order to evaluate their behaviour, with respect to that of the widely employed carbazole group, when used as photoconductive centres attached to a polymer chain. The obtained data show that photoconductivity and traps formation mechanism can be inferred as functions of the physico-chemical parameters (electric dipole moment and ionization potential) of the different groups and polymers involved. To this end such parameters have been carefully computed for a series of pyrrole, indole and carbazole derivatives. The 2,3-dimethylindole derivative appears to be particularly promising due to its electrooptical behaviour in the red absorption region where measurements have been accomplished and are shown to be consistent with the theoretical predictions. 
540 |a © 2013 by Walter de Gruyter GmbH & Co. 
700 1 |a Angelone  |D Rocco  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
700 1 |a Castè  |D Claudia  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
700 1 |a Castelvetro  |D Valter  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
700 1 |a Ciardelli  |D Francesco  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
700 1 |a Colligiani  |D Arturo  |u INFM, 56100 Pisa, Italy  |4 aut 
700 1 |a Greco  |D Francesco  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
700 1 |a Mazzotta  |D Alessandro  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
700 1 |a Ruggeri  |D Giacomo  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Angelone  |D Rocco  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Castè  |D Claudia  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Castelvetro  |D Valter  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Ciardelli  |D Francesco  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Colligiani  |D Arturo  |u INFM, 56100 Pisa, Italy  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Greco  |D Francesco  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Mazzotta  |D Alessandro  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Ruggeri  |D Giacomo  |u Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy; Fax +39-050-2219260  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t e-Polymers  |d De Gruyter  |g 4/1(2004-12-01), 863-877  |x 2197-4586  |q 4:1<863  |1 2004  |2 4  |o epoly 
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