Interfacial irregularity induced by hydrogen bonds at the interface in immiscible polymer blends

Verfasser / Beitragende:
[Yuka Kobori, Rei Yasumitsu, Isamu Akiba, Saburo Akiyama, Hironari Sano]
Ort, Verlag, Jahr:
2004
Enthalten in:
e-Polymers, 4/1(2004-12-01), 34-39
Format:
Artikel (online)
ID: 378903195
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024 7 0 |a 10.1515/epoly.2004.4.1.34  |2 doi 
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245 0 0 |a Interfacial irregularity induced by hydrogen bonds at the interface in immiscible polymer blends  |h [Elektronische Daten]  |c [Yuka Kobori, Rei Yasumitsu, Isamu Akiba, Saburo Akiyama, Hironari Sano] 
520 3 |a Effects of interactions at the interface on the morphologies of immiscible polymer blends were investigated using linear low-density polyethylene/poly(4- vinylphenol) (LLDPE/PVPh) and LLDPE/poly(methyl methacrylate) (LLDPE/PMMA) blends containing polyethylene-block-PMMA (PE-b-PMMA). In the case of LLDPE/ PMMA/PE-b-PMMA blends, in which there is no specific interaction at the interface, shapes of dispersed droplets were maintained and sizes were simply diminished with increasing PE-b-PMMA content. On the other hand, in the case of LLDPE/ PVPh/PE-b-PMMA, in which hydrogen bonds are formed between PVPh and PMMA blocks at the interface, we found irregularly undulated phase boundaries. 
540 |a © 2013 by Walter de Gruyter GmbH & Co. 
700 1 |a Kobori  |D Yuka  |u Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan  |4 aut 
700 1 |a Yasumitsu  |D Rei  |u Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan  |4 aut 
700 1 |a Akiba  |D Isamu  |u Faculty of Environmental Engineering, The University of Kitakyushu, 1-1 Hibikino, Wakamatsu, Kitakyushu, Fukuoka 808-0135, Japan; Fax +81-93-695-3385  |4 aut 
700 1 |a Akiyama  |D Saburo  |u Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan  |4 aut 
700 1 |a Sano  |D Hironari  |u Mitsubishi Kagaku Co. Ltd., Yokkaichi, Mie 510, Japan  |4 aut 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Kobori  |D Yuka  |u Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Yasumitsu  |D Rei  |u Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Akiba  |D Isamu  |u Faculty of Environmental Engineering, The University of Kitakyushu, 1-1 Hibikino, Wakamatsu, Kitakyushu, Fukuoka 808-0135, Japan; Fax +81-93-695-3385  |4 aut 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Sano  |D Hironari  |u Mitsubishi Kagaku Co. Ltd., Yokkaichi, Mie 510, Japan  |4 aut 
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