Removal of copper-based catalyst in atom transfer radical polymerization using different extraction techniques
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| 024 | 7 | 0 | |a 10.1515/epoly.2004.4.1.414 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1515/epoly.2004.4.1.414 | ||
| 245 | 0 | 0 | |a Removal of copper-based catalyst in atom transfer radical polymerization using different extraction techniques |h [Elektronische Daten] |c [Isabelle Ydens, Sébastien Moins, François Botteman, Philippe Degée, Philippe Dubois] |
| 520 | 3 | |a Several methods allowing the removal of copper-based ATRP active complexes from crude amino-functionalized polymethacrylate chains are compared. Among them, precipitation in basic medium is one of the most efficient techniques since it allows high recovery yields (above 90%) with a residual metal content as low as 5 ppm. Extraction methods such as liquid-liquid phase separation and dialysis but also selective adsorption on acidic macroporous ion exchange resin constitute other attractive alternatives. As far as water-insoluble polymers are concerned, catalyst adsorption on alumina remains the most universal method and provides acceptable recovery efficiency. However, we want to stress the key-importance of the experimental adsorption conditions and above all the relative content of alumina used for catalyst extraction. | |
| 540 | |a © 2013 by Walter de Gruyter GmbH & Co. | ||
| 700 | 1 | |a Ydens |D Isabelle |u Laboratory of Polymeric and Composite Materials, University of Mons-Hainaut, Place du Parc 20, 7000 Mons, Belgium; Fax 0032 (65) 37 34 84 |4 aut | |
| 700 | 1 | |a Moins |D Sébastien |u Laboratory of Polymeric and Composite Materials, University of Mons-Hainaut, Place du Parc 20, 7000 Mons, Belgium; Fax 0032 (65) 37 34 84 |4 aut | |
| 700 | 1 | |a Botteman |D François |u Laboratory of Polymeric and Composite Materials, University of Mons-Hainaut, Place du Parc 20, 7000 Mons, Belgium; Fax 0032 (65) 37 34 84 |4 aut | |
| 700 | 1 | |a Degée |D Philippe |u Laboratory of Polymeric and Composite Materials, University of Mons-Hainaut, Place du Parc 20, 7000 Mons, Belgium; Fax 0032 (65) 37 34 84 |4 aut | |
| 700 | 1 | |a Dubois |D Philippe |u Laboratory of Polymeric and Composite Materials, University of Mons-Hainaut, Place du Parc 20, 7000 Mons, Belgium; Fax 0032 (65) 37 34 84 |4 aut | |
| 773 | 0 | |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 414-420 |x 2197-4586 |q 4:1<414 |1 2004 |2 4 |o epoly | |
| 856 | 4 | 0 | |u https://doi.org/10.1515/epoly.2004.4.1.414 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1515/epoly.2004.4.1.414 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ydens |D Isabelle |u Laboratory of Polymeric and Composite Materials, University of Mons-Hainaut, Place du Parc 20, 7000 Mons, Belgium; Fax 0032 (65) 37 34 84 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Moins |D Sébastien |u Laboratory of Polymeric and Composite Materials, University of Mons-Hainaut, Place du Parc 20, 7000 Mons, Belgium; Fax 0032 (65) 37 34 84 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Botteman |D François |u Laboratory of Polymeric and Composite Materials, University of Mons-Hainaut, Place du Parc 20, 7000 Mons, Belgium; Fax 0032 (65) 37 34 84 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Degée |D Philippe |u Laboratory of Polymeric and Composite Materials, University of Mons-Hainaut, Place du Parc 20, 7000 Mons, Belgium; Fax 0032 (65) 37 34 84 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Dubois |D Philippe |u Laboratory of Polymeric and Composite Materials, University of Mons-Hainaut, Place du Parc 20, 7000 Mons, Belgium; Fax 0032 (65) 37 34 84 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 414-420 |x 2197-4586 |q 4:1<414 |1 2004 |2 4 |o epoly | ||
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