Metastable state of amphiphilic polysaccharide solutions
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| 024 | 7 | 0 | |a 10.1515/epoly.2004.4.1.408 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1515/epoly.2004.4.1.408 | ||
| 245 | 0 | 0 | |a Metastable state of amphiphilic polysaccharide solutions |h [Elektronische Daten] |c [Sébastien Simon, Georgeta Mocanu, Luc Picton, Didier Le Cerf, Guy Muller] |
| 520 | 3 | |a This communication reports the time-dependent viscometric behaviour of amphiphilic pullulan (with varied amount of grafted octyl groups, C8) solutions as a function of age and temperature. For lower C8 amount, no ageing effects were observed. With high amount of octyl-bearing groups, the solution exhibits a strong increase of viscosity caused by an increase of intermolecular associations and the simultaneous decrease of intramolecular associations. After longer time, a collapse of chains has been observed. This behaviour is favoured with concentration and temperature. These results evidence the metastable character of amphiphilic polymers in aqueous solution. | |
| 540 | |a © 2013 by Walter de Gruyter GmbH & Co. | ||
| 700 | 1 | |a Simon |D Sébastien |u Laboratoire Polymères, Biopolymères, Membranes U.M.R. 6522, CNRS-Université de Rouen, 76821 Mont-Saint-Aignan, France; Fax +33 235 14 65 43 |4 aut | |
| 700 | 1 | |a Mocanu |D Georgeta |u ‘Petru Poni' Institute of Macromolecular Chemistry, 6600 Iasi, Romania; Fax +40 232 211 299 |4 aut | |
| 700 | 1 | |a Picton |D Luc |u Laboratoire Polymères, Biopolymères, Membranes U.M.R. 6522, CNRS-Université de Rouen, 76821 Mont-Saint-Aignan, France; Fax +33 235 14 65 43 |4 aut | |
| 700 | 1 | |a Le Cerf |D Didier |u Laboratoire Polymères, Biopolymères, Membranes U.M.R. 6522, CNRS-Université de Rouen, 76821 Mont-Saint-Aignan, France; Fax +33 235 14 65 43 |4 aut | |
| 700 | 1 | |a Muller |D Guy |u Laboratoire Polymères, Biopolymères, Membranes U.M.R. 6522, CNRS-Université de Rouen, 76821 Mont-Saint-Aignan, France; Fax +33 235 14 65 43 |4 aut | |
| 773 | 0 | |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 408-413 |x 2197-4586 |q 4:1<408 |1 2004 |2 4 |o epoly | |
| 856 | 4 | 0 | |u https://doi.org/10.1515/epoly.2004.4.1.408 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1515/epoly.2004.4.1.408 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Simon |D Sébastien |u Laboratoire Polymères, Biopolymères, Membranes U.M.R. 6522, CNRS-Université de Rouen, 76821 Mont-Saint-Aignan, France; Fax +33 235 14 65 43 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Mocanu |D Georgeta |u ‘Petru Poni' Institute of Macromolecular Chemistry, 6600 Iasi, Romania; Fax +40 232 211 299 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Picton |D Luc |u Laboratoire Polymères, Biopolymères, Membranes U.M.R. 6522, CNRS-Université de Rouen, 76821 Mont-Saint-Aignan, France; Fax +33 235 14 65 43 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Le Cerf |D Didier |u Laboratoire Polymères, Biopolymères, Membranes U.M.R. 6522, CNRS-Université de Rouen, 76821 Mont-Saint-Aignan, France; Fax +33 235 14 65 43 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Muller |D Guy |u Laboratoire Polymères, Biopolymères, Membranes U.M.R. 6522, CNRS-Université de Rouen, 76821 Mont-Saint-Aignan, France; Fax +33 235 14 65 43 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 408-413 |x 2197-4586 |q 4:1<408 |1 2004 |2 4 |o epoly | ||
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