caa a22 4500 378903470 CHVBK 20180305123524.0 cr unu---uuuuu 161128e20041201xx s 000 0 eng 10.1515/epoly.2004.4.1.579 doi (NATIONALLICENCE)gruyter-10.1515/epoly.2004.4.1.579 Polymerization of styrene using 1,1,2,2-tetraphenyl-1,2- ethanediol as initiator in the presence of 2,2,6,6-tetramethyl- 1-piperidinyloxy [Elektronische Daten] [Gang Wang, Xiulin Zhu, Dijun Hu, Zhengping Cheng, Jian Zhu] The bulk polymerization of styrene using 1,1,2,2-tetraphenyl-1,2-ethanediol as initiator in the presence of 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) was investigated. The results show that polymerization proceeded in a controlled/ 'living' way, i.e., polymerization rate is first order with respect to monomer concentration. Molecular weights increase linearly with conversion and molecular weight distributions are relatively low (Mw/Mn = 1.10 - 1.35). Well-defined polystyrenes with α-hydrogen and TEMPO end groups were obtained. © 2013 by Walter de Gruyter GmbH & Co. Wang Gang School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P. R. China; Fax 86-512-65112796 aut Zhu Xiulin School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P. R. China; Fax 86-512-65112796 aut Hu Dijun School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P. R. China; Fax 86-512-65112796 aut Cheng Zhengping School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P. R. China; Fax 86-512-65112796 aut Zhu Jian School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P. R. China; Fax 86-512-65112796 aut e-Polymers De Gruyter 4/1(2004-12-01), 579-586 2197-4586 4:1<579 2004 4 epoly https://doi.org/10.1515/epoly.2004.4.1.579 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1515/epoly.2004.4.1.579 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Gang School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P. R. China; Fax 86-512-65112796 aut NATIONALLICENCE 700 1- Zhu Xiulin School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P. R. China; Fax 86-512-65112796 aut NATIONALLICENCE 700 1- Hu Dijun School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P. R. China; Fax 86-512-65112796 aut NATIONALLICENCE 700 1- Cheng Zhengping School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P. R. China; Fax 86-512-65112796 aut NATIONALLICENCE 700 1- Zhu Jian School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P. R. China; Fax 86-512-65112796 aut NATIONALLICENCE 773 0- e-Polymers De Gruyter 4/1(2004-12-01), 579-586 2197-4586 4:1<579 2004 4 epoly CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter