Evolution of the partition coefficients of peroxide initiators during the synthesis of high-impact polystyrene
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| 024 | 7 | 0 | |a 10.1515/epoly.2004.4.1.93 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1515/epoly.2004.4.1.93 | ||
| 245 | 0 | 0 | |a Evolution of the partition coefficients of peroxide initiators during the synthesis of high-impact polystyrene |h [Elektronische Daten] |c [Denis Bertin, Fabien Coutand, Michel Duc, Christophe Galindo, Didier Gigmès, Sylvain Marque, Paul Tordo, Bruno Vuillemin] |
| 520 | 3 | |a The partition coefficient K of commercially available peroxide initiators between polystyrene (PS) and polybutadiene (PB) phases during the synthesis of high-impact PS is investigated with model systems. Influences of styrene conversion and peroxide initiator concentration on K are studied for two different PBs. It is shown that K varies linearly with conversion, exhibits a logarithmic behaviour according to the peroxide initiator concentration, and is influenced by the microstructure of PB. Nevertheless, these effects are weak. For any peroxide initiator family studied, i.e., percarbonate, perester, and perdiketal, the values of K are close to 1, showing that peroxide initiators are evenly distributed between the PS and PB phases, before the phase inversion. | |
| 540 | |a © 2013 by Walter de Gruyter GmbH & Co. | ||
| 700 | 1 | |a Bertin |D Denis |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | |
| 700 | 1 | |a Coutand |D Fabien |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | |
| 700 | 1 | |a Duc |D Michel |u ATOFINA, Groupement de Recherches de Lacq, route de Bayonne, 64170 Lacq, France |4 aut | |
| 700 | 1 | |a Galindo |D Christophe |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | |
| 700 | 1 | |a Gigmès |D Didier |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | |
| 700 | 1 | |a Marque |D Sylvain |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | |
| 700 | 1 | |a Tordo |D Paul |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | |
| 700 | 1 | |a Vuillemin |D Bruno |u ATOFINA, Groupement de Recherches de Lacq, route de Bayonne, 64170 Lacq, France |4 aut | |
| 773 | 0 | |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 93-102 |x 2197-4586 |q 4:1<93 |1 2004 |2 4 |o epoly | |
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| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1515/epoly.2004.4.1.93 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Bertin |D Denis |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Coutand |D Fabien |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Duc |D Michel |u ATOFINA, Groupement de Recherches de Lacq, route de Bayonne, 64170 Lacq, France |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Galindo |D Christophe |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Gigmès |D Didier |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Marque |D Sylvain |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Tordo |D Paul |u UMR 6517 Equipe CROPS, case 542, Université de Provence, Avenue de l'escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; Fax 33-4-91-98-85-12 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Vuillemin |D Bruno |u ATOFINA, Groupement de Recherches de Lacq, route de Bayonne, 64170 Lacq, France |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 93-102 |x 2197-4586 |q 4:1<93 |1 2004 |2 4 |o epoly | ||
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