Formation of superlattices in blends of 3-miktoarm star terpolymers with diblock copolymers
Gespeichert in:
Verfasser / Beitragende:
[Volker Abetz, Shimei Jiang]
Ort, Verlag, Jahr:
2004
Enthalten in:
e-Polymers, 4/1(2004-12-01), 599-607
Format:
Artikel (online)
Online Zugang:
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| 245 | 0 | 0 | |a Formation of superlattices in blends of 3-miktoarm star terpolymers with diblock copolymers |h [Elektronische Daten] |c [Volker Abetz, Shimei Jiang] |
| 520 | 3 | |a In this contribution we report on the morphological structures formed in blends of microphase-separated 3-miktoarm star terpolymers of polystyrene-armpolybutadiene- arm-poly(2-vinylpyridine) (SBV*) and polystyrene-block-polybutadiene (SB), polystyrene-block-poly(2-vinylpyridine) (SV), poly(2-vinylpyridine)- block-poly(cyclohexyl methacrylate) (VC) diblock copolymers. The morphologies are characterized by transmission electron microscopy. Blends with similar morphologies as known from linear triblock terpolymers are found, like core-shell structures based on cylinders or gyroids. Other blends show very distorted morphologies, or morphologies similar to the ones found for pure 3-miktoarm star terpolymers. While attractive interactions between blocks of the two species enhance the formation of common superlattices, blends with too large diblock copolymers tend to macrophase-separate. | |
| 540 | |a © 2013 by Walter de Gruyter GmbH & Co. | ||
| 700 | 1 | |a Abetz |D Volker |u Makromolekulare Chemie II, Universität Bayreuth, 95440 Bayreuth, Germany |4 aut | |
| 700 | 1 | |a Jiang |D Shimei |u Makromolekulare Chemie II, Universität Bayreuth, 95440 Bayreuth, Germany |4 aut | |
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| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Abetz |D Volker |u Makromolekulare Chemie II, Universität Bayreuth, 95440 Bayreuth, Germany |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Jiang |D Shimei |u Makromolekulare Chemie II, Universität Bayreuth, 95440 Bayreuth, Germany |4 aut | ||
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